Abstract
In the Ohmine granitic rocks of Kii Peninsula, central Japan, ilmenite, rutile, pyrrhotite, pyrite and chalcopyrite commonly occur, but no magnetite is present. Their primary paragenetic relations were confirmed by examining their mode of occurrences as inclusion species in major silicate minerals and the phase relations in the Cu-Fe-S system, though their parageneses changed in cooling of the rocks. This makes it possible to estimate the fugacities of oxygen and sulfur in the granitic rocks based upon their paragenetic relations, and to discuss the nature of volatiles in the granitic rocks.
Significant subsolidus reactions for sulfide minerals continued until the rocks cooled below 300° C and took place in two types of mineral grains, in groundmass and as inclusions. The removal of sulfur and copper through the silicate crystals was too easy to preserve the chemistry of sulfides included in silicates.
Similar content being viewed by others
References
Arnold RG (1969) Pyrrhotite phase relations below 304±6° C at 1 atm total pressure. Econ Geol 64:405–419
Cabri JL (1973) New data on phase relations in the Cu-Fe-S system. Econ Geol 68:443–454
Carmichael ISE (1967) The iron-titanium oxides of salic volcanic rocks and their associated ferromagnesian silicates. Contrib Mineral Petrol 14:36–64
Chappel BW and White AJR (1974) Two contrastings granite types. Pacific Geol 8:173–174
Craig JR and Scott SD (1974) Sulfide phase equilibria. In PH Ribbe (ed) Short Course Notes 1, Sulfide mineralogy. Mineral Soc Am:CS1–CS110
Czamanske GK and Mihálik P (1972) Oxidation during magmatic differentiation Finnmarka complex, Oslo area, Norway: Part 1 The opaque oxides. J Petrol 13:493–509
Flood RH and Shaw SE (1977) Two ‘S-type’ granite suites with low initital87Sr/86Sr ratios from the New England batholith, Australia. Contrib Mineral Petrol 61:163–173
Ishihara S (1977) The magnetite-series and ilmenite-series granitic rocks. Mining Geol 27:293–305
Itaya T (1975) Pyrrhotite from the Sanbagawa pelitic schists of the Shiragayama area, central Shikoku, Japan. Mineral J 8:25–37
Itaya T and Banno S (1980) Paragenesis of titanium-bearing accessories in pelitic schists of the Sanbagawa metamorphic belt, central Shikoku, Japan. Contrib Mineral Petrol 73:267–276
Itaya T, Nagao K, Murata M and Ogata K (1982) Rare gas composition and K-Ar ages of I- and S-types in the Ohmine granitic rocks, central Kii Peninsula, Japan. Abstract in Fifth International Conference on Geochronology, Cosmochronology and Isotope Geology: 164–165
Kaneko K (1967) Ômine igneous complex in central Kii Peninsula. Rep Fac Education, Miyazaki Univ, No 22:18–32
Kawasaki M (1980a) Online acid rocks, Kii Peninsula. Geology and major element chemistry. J Jpn Assoc Min Pet Econ Geol 75:86–102
Kawasaki M (1980b) Ômine acid rocks, Kii Peninsula. Mineralogy. J Jpn Assoc Min Pet Econ Geol 75:146–159
Kawasaki M (1981) Ômine acid rocks, Kii Peninsula. Petrogenesis. J Jpn Assoc Min Pet Econ Geol 76:195–206
Murata M (1982a) S-type and I-type granitic rocks of the Ohmine district central Kii Peninsula. J Jpn Assoc Min Pet Econ Geol 77:267–277
Murata M (1982b) Petrology of Tertiary granitic rocks in the Ohmine district, central Kii Peninsula. Ph. D. thesis, Tohoku University
Nakazawa H and Morimoto N (1970) Pyrrhotite phase relations below 320° C. Proc Jpn Acad 46:678–683
Nakazawa H and Morimoto N (1971) Phase relations and superstructures of pyrrhotite Fe1-xS. Mater Res Bull 6:345–358
Ohmoto H and Kerrick D (1977) Devolatisation equilibria in graphitic systems. Am J Sci 277:1013–1044
Okamoto Y, Homma H, Murata M and Iizumi S (1982) Oxygen isotopic ratio of granitic rocks in the Outer zone of South western Japan, abst in 89th Ann Meeting, Geol Soc Jpn, p 418
O'Neil JR and Chappell BW (1977) Oxygen and hydrogen isotope relations in the Berridale batholith. J Geol Soc London, 133:559–571
O'Neil JR, Shaw SE and Flood RH (1977) Oxygen and hydrogen isotope compositions as indicators of granite genesis in the New England batholith, Australia. Contrib Mineral Petrol 62:313–328
Ono K and Moriyama J (1973) Thermodynamic study on the Fe-FeO-TiO2 system. J Mineral Metal Inst Jpn 89:313–316
Robie RA and Waldbaum DR (1968) Thermodynamic properties of minerals and related substances at 298.15° K (25° C) and one atmosphere (1.013 bars) pressure and at higher temperatures. US Geol Surv Bull 1259:256 p
Sasaki A and Ishihara S (1979) Sulfur isotopic composition of the magnetite-series and ilmenite-series granitoids in Japan. Contrib Mineral Petrol 68:107–115
Sato M (1972) Intrinsic oxygen fugacities of iron-bearing oxide and silicate minerals under low total pressure. Geol Soc Am Mem 135:289–307
Sato M (1979) Oxygen fugacity of basaltic magmas and the role of gasforming elements. Geophys Res Lett 5:447–449
Tainosho Y (1971) Petrology of the Ibaragi granitic complex in the northern part of Osaka Prefecture, Japan. J Geol Soc Jpn 77:57–70
Toulmin P III and Barton PB Jr (1964) A thermodynamic study of pyrite and pyrrhotite. Geochim Cosmochim Acta 28:641–671
Tsusue A (1973) The distribution of manganese and iron between ilmenite and granitic magma in the Osumi Peninsula, Japan. Contrib Mineral Petrol 40:305–314
Tsusue A and Ishihara S (1974) The iron-titanium oxide in the granitic rocks of Southwest Japan. Mining Geol 24:13–30
Ueno T and Sugaki A (1981) Relationship between temperature and sulfur fugacity on the mineral assemblages of chalcopyritepyrrhotite and cubanite-chalcopyrite-pyrrhotite. J Jpn Assoc Min Pet Econ Geol 76:207–213
White AJR, Beam SD and Cramer JJ (1977) Granitoid types and mineralization with special reference to tin. in Plutonism in Relation to Volcanism and metamorphism (ed) by N. Yamada, Proc 7th CPPP Mtg Toyama 89–100
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Murata, M., Itaya, T. & Ueda, Y. Sulphide and oxide minerals from the Ohmine granitic rocks in Kii Peninsula, central Japan, and their primary paragenetic relations. Contr. Mineral. and Petrol. 84, 58–65 (1983). https://doi.org/10.1007/BF01132330
Issue Date:
DOI: https://doi.org/10.1007/BF01132330