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Paragenesis of titanium-bearing accessories in pelitic schists of the Sanbagawa metamorphic belt, Central Shikoku, Japan

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Abstract

In pelitic schists of the Sanbagawa metamorphic belt, sphene, rutile, and ilmenite occur as discrete grains, in composite aggregates, and as inclusions in garnets. Textural relationships, disposition of inclusions in garnet, and the compositions of ilmenites suggest that the titanium-bearing accessories stable at the peak metamorphic conditions were as follows: sphene in the chlorite zone, sphene plus rutile in the garnet zone, and ilmenite in the highest grade of the belt, the biotite zone. Rutile appears in the garnet zone as a consequence of Ca incorporation into garnet and a progressive increase in \(f_{{\text{CO}}_{\text{2}} }\).

Retrograde reactions were responsible for the composite aggregates of rutile, sphene and ilmenite and these must be carefully evaluated before prograde relationships between titanium-bearing accessories can be properly understood.

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References

  • Albee AL (1972) Metamorphism of pelitic schists: reaction relations of chloritoid and staurolite. Bull Geol Soc Am 83:3249–3268

    Google Scholar 

  • Banno S, Higashino T, Otsuki M, Nakajima T, Itaya T (1978) Thermal structure of the Sanbagawa belt in central Shikoku. J Phys Earth 26 (Suppl):345–356

    Google Scholar 

  • Banno S, Kurata H (1972) Distribution of Ca in zoned garnet of low-grade pelitic schists. J Geol Soc Jpn 78:507–512

    Google Scholar 

  • Bence AE, Albee AL (1968) Empirical correction factors for the electron microanalysis for silicates and oxides. J Geol 76:382–403

    Google Scholar 

  • Ernst WG (1972) CO2-poor composition of the fluid attending Franciscan and Sanbagawa low-grade metamorphism. Geochim Cosmochim Acta 36:497–504

    Article  Google Scholar 

  • Ernst WG, Seki Y, Onuki H, Gilbert MC (1970) Comparative study of low-grade metamorphism in the California Coast Range and the outer metamorphic belt of Japan. Geol Soc Am, Mem 124

  • Ghent E (1975) Temperature, pressure, and mixed volatile equilibria attending metamorphism of staurolite-kyanite bearing assemblages, Esplande Range, British Columbia. Bull Geol Soc Am 86:1654–1660

    Google Scholar 

  • Guidotti CV (1974) Transition from staurolite to sillimanite zone, Rangely quardrangle, Main. Bull Geol Soc Am 85:465–490

    Google Scholar 

  • Higashino T (1975) Biotite zone of Sanbagawa metamorphic terrain in the Shiragayama area, central Shikoku, Japan. J Geol Soc Jpn 81:653–670

    Google Scholar 

  • Itaya T (1975) Pyrrhotite from the Sanbagawa pelitic schists of the Shiragayama area, central Shikoku, Japan. Mineral J Japan 8:25–37

    Google Scholar 

  • Izawa E (1968) Carbonaceous matter in some metamorphic rocks in Japan. J Geol Soc Jpn 74:427–432

    Google Scholar 

  • Kanehira K, Banno S, Nishida K (1964) Sulfide and oxide minerals in some metamorphic terrains in Japan. Jpn J Geol Geogr 35:175–191

    Google Scholar 

  • Kawachi Y (1968) Large-scale overturned structure in the Sanbagawa metamorphic zone in central Shikoku. J Geol Soc Jpn 74:607–616

    Google Scholar 

  • Kurata H (1972) Local chemical heterogeneity of chlorites in Sanbagawa pelitic schists from the Sazare area, central Shikoku. J Geol Soc Jpn 78:653–657

    Google Scholar 

  • Kurata H, Banno S (1974) Low-grade progressive metamorphism of pelitic schists of the Sazare area, Sanbagawa metamorphic terrain in central Shikoku, Japan. J Petrol 15:361–382

    Google Scholar 

  • Mariko T, Tanaka K, Itaya T (1975) Oxide and sulfide minerals in pelitic and psammitic schists from the Nagatoro district, Saitama prefecture, Japan. J Jpn Assoc Mineral Petr Econ Geol 70:413–424

    Google Scholar 

  • Schuiling RD, Vink BW (1967) Stability relations of some titaniumminerals (sphene, perovskite, rutile, anatase). Geochim Cosmochim Acta 31:2399–2411

    Google Scholar 

  • Toriumi M (1975) Petrological study of the Sanbagawa metamorphic rocks in the Kanto mountains, central Japan. The University Museum of the Univ of Tokyo, Bull No 9

  • Yui S (1968) Results of equilibrium calculation on the reaction between graphite and a H2O-CO2 fluid. J Mineral Coll Akita Univ Ser A, IV: No 3, 29–39

    Google Scholar 

  • Yui S, Shoji T (1976) Computer programs used in the ZAF correction. J Mineral Soc Tokyo (Spec Issue) 12:70–81

    Google Scholar 

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Itaya, T., Banno, S. Paragenesis of titanium-bearing accessories in pelitic schists of the Sanbagawa metamorphic belt, Central Shikoku, Japan. Contr. Mineral. and Petrol. 73, 267–276 (1980). https://doi.org/10.1007/BF00381445

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  • DOI: https://doi.org/10.1007/BF00381445

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