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Metal-containing monomers. Part 1. Spatial and electronic structures of cobalt(II) and nickel(II) complexes with acrylamide and of their polymers

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The spatial and electronic structures of the complexes [Co(AAm)4(H2O)2](NO3)2 (1), Co(AAm)4Cl2 (2), [Ni(AAm)4(H2O)2](NO3)2 (3) and Ni(AAm)4Cl2 (4), where AAm is acrylamide, and the products of their radical, frontal and post-grafting polymerization have been studied by electronic spectroscopy. The complexes (1), (3) and (4) were found to have pseudooctahedral structures in both the solid and solution phases. A change in the spatial structure of complex (2) was established in going from the crystal (tetragonally distorted octahedral) to solution (tetrahedral). The coordination environment of the metal centre does not change markedly during polymerization of the metal-containing monomers.

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Authors and Affiliations

  1. Department of Chemistry, State Pedagogical Institute, Engelsa 33, 344082, Rostov-on-Don, USSR

    Igor E. Uflyand & Andrei G. Starikov

  2. Institute of Chemical Physics, Academy of Sciences, 142432, Chernogolovka, Moscow Region, USSR

    Vladimir S. Savostjanov & Anatoly D. Pomogailo

Authors
  1. Igor E. Uflyand
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  2. Andrei G. Starikov
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  3. Vladimir S. Savostjanov
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  4. Anatoly D. Pomogailo
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Uflyand, I.E., Starikov, A.G., Savostjanov, V.S. et al. Metal-containing monomers. Part 1. Spatial and electronic structures of cobalt(II) and nickel(II) complexes with acrylamide and of their polymers. Transition Met Chem 16, 126–129 (1991). https://doi.org/10.1007/BF01127887

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  • DOI: https://doi.org/10.1007/BF01127887

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