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Verfeinerung der Kristallstruktur von Kupfer(II)-hydroxichlorid, Cu(OH)Cl

Crystal structure refinement of copper(II) hydroxichloride, Cu(OH)Cl

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Abstract

The crystal structure of Cu(OH)Cl [a=5.555 (2) Å,b=6.671 (4) Å,c=6.127 (2) Å, β=114.88 (3)°, space group P2I/a,Z=4] was refined for 810 observed reflections with sin ϑ/λ≤0.80 Å−1 toR=0.035. Crystals were synthesized under hydrothermal conditions. The copper atom is planar four coordinated by three oxygen atoms and one chlorine atom; two further chlorine atoms complete its coordination. The copper polyhedra share edges to build up sheets, which are connected by hydrogen bonds to the chlorine atoms of adjacent sheets.

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  1. Institut für Mineralogie und Kristallographie, Universität Wien, A-1010, Wien, Österreich

    Herta Effenberger

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  1. Herta Effenberger
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Effenberger, H. Verfeinerung der Kristallstruktur von Kupfer(II)-hydroxichlorid, Cu(OH)Cl. Monatsh Chem 115, 725–730 (1984). https://doi.org/10.1007/BF01120967

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