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Organic derivatives of antimony

3. Alkoxy and chloroalkoxy derivatives of antimony

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The action of an excess of chlorine on the corresponding alkoxy- and chloroalkoxy derivatives of Sb(III) produced trichlorodimethoxy-, dichlorotrimethoxy-, and trichlorodiethoxyantimony, which have not been described in the literature, as well as tetrachloromethoxy- and dichlorotriethoxyantimony.

  2. 2.

    The action of acetyl chloride on pentaethoxyantimony yielded chlorotetraethoxyantimony.

  3. 3.

    The ester interchange of pentaethoxyantimony with methanol yielded pentamethoxyantimony.

  4. 4.

    The reaction of SbCl3 with trimethoxy- and triethoxyantimony produced chlorodimethoxy-, dichloromethoxy-, and chlorodiethoxyantimony.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 901–904, April, 1977.

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Arbuzov, B.A., Mareev, Y.M. & Vinogradova, V.S. Organic derivatives of antimony. Russ Chem Bull 26, 824–828 (1977). https://doi.org/10.1007/BF01108208

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  • DOI: https://doi.org/10.1007/BF01108208

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