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Synthesis of tetracarboxylic acid dianhydrides by aromatization of adducts of bis-furan compounds with maleic anhydride

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Dehydration (aromatization) of bis-adducts formed by Diels-Alder reaction between maleic anhydride and bisfuran compounds gives dianhydrides of aromatic tetracarboxylic acids with different structures, which are suitable for the preparation of thermostable polymers.

  2. 2.

    The nonaromatized bis-adducts can be used for the one-step preparation of polyimides and polyimidazopyrrolones in polyphosphoric acid, since they are aromatized under the polymersynthesis conditions.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    A. A. Berlin, B. I. Liogon'kii, B. I. Zapadinskii, E. A. Kazantseva & A. O. Stankevich

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  1. A. A. Berlin
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  2. B. I. Liogon'kii
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  3. B. I. Zapadinskii
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  4. E. A. Kazantseva
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  5. A. O. Stankevich
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 867–874, April, 1977.

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Berlin, A.A., Liogon'kii, B.I., Zapadinskii, B.I. et al. Synthesis of tetracarboxylic acid dianhydrides by aromatization of adducts of bis-furan compounds with maleic anhydride. Russ Chem Bull 26, 790–797 (1977). https://doi.org/10.1007/BF01108202

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  • DOI: https://doi.org/10.1007/BF01108202

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