Conclusions
-
1.
The alteration of the geminal2JPCH constant resulting from change in the polarity of the medium is determined by the position of the point of conformational equilibrium.
-
2.
Spatial structures have been determined for organophosphorus compounds containing several chloromethyl groups.
Similar content being viewed by others
Literature cited
O. A. Raevskii, F. G. Khalitov, A. N. Vereshchagin, and I. M. Vetluzhskikh, Izv. Akad. Nauk SSSR, Ser. Khim., 2446 (1972).
O. A. Raevskii, A. N. Vereshchagin, F. G. Khalitov, and Yu. A. Donskaya, Izv. Akad. Nauk SSSR, Ser. Khim., 710 (1972).
O. A. Raevskii, A. N. Vereshchagin, F. G. Khalitov, and E. N. Tsvetkov, Izv. Akad. Nauk SSSR, Ser. Khim., 995 (1973).
O. A. Raevskii, A. N. Vereshchagin, Yu. A. Donskaya, F. G. Khalitov, and E. N. Tsvetkov, Izv. Akad. Nauk SSSR, Ser. Khim., 878 (1974).
O. A. Raevskii and A. N. Vereshchagin, in: Problems in Sterochemistry [in Russian], Vol. 2, Vysshaya Shkola, Kiev (1972), p. 38.
B. I. Ionin and B. A. Ershov, NMR Spectroscopy in Organic Chemistry [in Russian], Khimiya, Leningrad (1967), p. 294.
C. Altona, H. R. Buys, H. J. Hageman, and E. Havinga, Tetrahedron23, 2265 (1967).
J. P. Albrand, D. Gagnaire, and J. B. Robert, Chem. Commun., 1469 (1968); J. P. Albrand, D. Gagnaire, J. Martin, and J. B. Robert, Bull. Soc. Chim. France, 40 (1969).
D. G. Rowsell, J. Mol. Spectrosc.,23, 32 (1967); L. I. Vinogradov, Yu. Yu. Samitov, A. Ya. Kessel', L. V. Nesterov, and V. B. Mardanov, Teor. Eksp. Khim.,6, 103 (1970); L. I. Vinogradov, Yu. Yu. Samitov, I. Ya. Kuramshin, A. A. Muratova, and A. N. Pudovik, Zh. Obshch. Khim.,44, 37 (1974).
R. K. Safiullin, R. A. Aminova, and Yu. Yu. Samitov, Zh. Struk. Khim.,16, 42 (1975); R. K. Safiullin, Dissertation, Kazan (1975).
A. V. Iogansen, Opt. Spektrosk.16, 813 (1964).
O. A. Raevskii, F. G. Khalitov, N. G. Mumzhieva, M. M. Gilyazov, D. U. Zakirov, I. A. Safin, and A. V. Aganov, Izv. Akad. Nauk SSSR, Ser. Khim., 2701 (1976).
J. W. Emsley et al., High-Resolution Nuclear Resonance Spectroscopy, Vol. 1, Pergamon (1966).
Yu. V. Linnik, Least-Squares Methods and the Principles of the Theory of Data Analysis [in Russian], Fizmatgiz, Moscow (1962).
B. I. Lonin and T. N. Timofeeva, Usp. Khim.,41, 758 (1972).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 797–802, April, 1977.
Rights and permissions
About this article
Cite this article
Raevskii, O.A., Mumzhieva, N.G., Aleksandrova, N.A. et al. A combined NMR and IR spectroscopic study of the sterochemistry of certain organophosphorus compounds containing halomethyl groups. Russ Chem Bull 26, 726–730 (1977). https://doi.org/10.1007/BF01108189
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01108189