Conclusions
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1.
C-H acids of a number of polynitroalkanes with ether-type solvents form intermolecular hydrogen bonds, forming stable complexes with a 1∶1 composition.
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2.
The replacement of the methyl group in the α-position of C-H acids by a nitro group increases their proton donor capacity and the energy of the hydrogen bond,
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3.
The change in the structure of the investigated ethers-hydrogen acceptors — leads to a change in the value of the dissociation constant of the complexes and does not affect the shift of the C-D band and, consequently, the energy of the hydrogen bond.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 527–529, March, 1976.
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Golub, Y.M., Ershov, M.V., Slovetskii, V.I. et al. Complex formation of trinitromethane and 1,1-dinitroethane with etheetype solvents. Russ Chem Bull 25, 509–511 (1976). https://doi.org/10.1007/BF01106642
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DOI: https://doi.org/10.1007/BF01106642