Summary
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1.
Hydrides of the intermetallides Zr-Ni, Zr-Co, Hf-Ni, and Hf-Co are active in the synthesis of methane from CO2 and H2.
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2.
The compositions of the gas mixtures after hydrogenation of CO2 in the interval 300–500°C at a space velocity of 1000 h−1 correspond well to equilibrium compositions derived from thermodynamic calculations.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2529–2531, November, 1981.
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Lapidus, A.L., Bruk, I.A., Mal'tsev, V.V. et al. Hydrogenation of carbon dioxide on hydrides of intermetallides. Russ Chem Bull 30, 2091–2093 (1981). https://doi.org/10.1007/BF01094636
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DOI: https://doi.org/10.1007/BF01094636