Conclusions
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1.
The IR spectra have been obtained of RR-(+)-tartaric acid chemisorbed on Cu, Ni, and Cu-Ni catalysts supported on Aerosil.
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2.
We have considered the probable structure of the asymmetric clusters that carry out asymmetric hydrogenation, and of the intermediate heteroligand complexes through which the enantioselective reaction proceeds.
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Deceased.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2519–2523, November, 1981.
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Vedenyapin, A.A., Klabunovskii, E.I. & Vlasenko, Y.V. Structure of asymmetric clusters that carry out enantioselective heterogeneous catalysis. Russ Chem Bull 30, 2083–2086 (1981). https://doi.org/10.1007/BF01094634
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DOI: https://doi.org/10.1007/BF01094634