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Silicon-containing radicals and diradicals with 3,5-DI-tert-butylpyrocatechol ligands

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    ESR spectrometry has been used to investigate the radicals and diradicals formed by the interaction of silicon 3,3′,5,5′-tetra-tert-butylpyrocatecholate with substituted orthoquinones and stable radicals.

  2. 2.

    On the basis of the temperature evolution of the ESR spectra, it has been concluded that two rotamers are present in the radicals that are formed. The thermodynamic characteristics of the reversible equilibrium between the rotamers have been obtained.

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Literature cited

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    A. K. Chekalov, A. I. Prokof'ev, N. N. Bubnov, S. P. Solodovnikov, A. A. Zhdanov & M. I. Kabachnik

Authors
  1. A. K. Chekalov
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  2. A. I. Prokof'ev
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  3. N. N. Bubnov
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  4. S. P. Solodovnikov
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  5. A. A. Zhdanov
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  6. M. I. Kabachnik
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2497–2505, November, 1981.

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Chekalov, A.K., Prokof'ev, A.I., Bubnov, N.N. et al. Silicon-containing radicals and diradicals with 3,5-DI-tert-butylpyrocatechol ligands. Russ Chem Bull 30, 2064–2071 (1981). https://doi.org/10.1007/BF01094630

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  • DOI: https://doi.org/10.1007/BF01094630

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