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Synthesis and Thermal Decomposition Studies of Silicon (IV) Compounds with N,N’-Bis(Salicylidene)Ethylenediimine

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Abstract

The silicon (IV) compounds possessing SiN4O2 (6), SiN2O2C2 (7, 8), SiN2O2CCl (9) and SiN4O4 (10) coordinating frameworks have been synthesized in high yield by the reaction of the O,N,N,O- donor salen-type ligand N,N’-bis(salicylidene)ethylenediimine L with different silanes i.e. diethoxydiisocyanatosilane-(C2H5O)2Si(NCO)2 1, dichlorodiphenylsilane-Ph2SiCl2 2, dichloromethyl- phenylsilane-MePhSiCl2 3, trichlorophenylsilane-PhSiCl3 4 and silicon tetrachloride-SiCl4 5. The compounds 6–10 have been characterized by elemental analysis, IR, 1H, 13C and 29Si NMR and mass spectrometry. The decomposition reactivity of these compounds has been studied using a Thermal Gravimetric Analyzer (TGA) at a heating rate of 10°C/minute in an inert atmosphere.

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Authors and Affiliations

  1. Department of Chemistry, Panjab University, Chandigarh, 160014, India

    Gurjaspreet Singh, Amandeep Saroa, Sheenam Girdhar &  Promila

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  1. Gurjaspreet Singh
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  2. Amandeep Saroa
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  3. Sheenam Girdhar
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  4. Promila
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Correspondence to Gurjaspreet Singh.

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Singh, G., Saroa, A., Girdhar, S. et al. Synthesis and Thermal Decomposition Studies of Silicon (IV) Compounds with N,N’-Bis(Salicylidene)Ethylenediimine. Silicon 9, 159–163 (2017). https://doi.org/10.1007/s12633-015-9325-4

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  • DOI: https://doi.org/10.1007/s12633-015-9325-4

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