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Infrared absorption spectra of 1,1-substituted silicacyclobutanes, silicacyclopentanes, and the corresponding polymers

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The IR absorption spectra of a series of 1,1-substituted silicacyclobutanes, silicacyclopentanes, and the corresponding polymers were obtained and investigated.

  2. 2.

    The frequencies characterizing the 1,1-substituted silicacyclobutane and silicacyclopentane rings were established.

  3. 3.

    As a result of an investigation of the IR spectra of the polymers produced by thermal polymerization of a number of 1,1-substituted silicacyclobutanes, it was established that the polymerization products are heterochain polymers with the structural fragment

    as the unit of the basic chain.

  4. 4.

    In the catalytic polymerization of 1,1-substituted silicacyclopentanes, heterochain polymers are formed, with the structural fragment

    as the unit of the basic chain.

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Literature cited

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences, USSR

    N. S. Nametkin, V. D. Oppengeim, V. I. Zav'yalov, K. S. Pushchevaya & V. M. Vdovin

Authors
  1. N. S. Nametkin
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  2. V. D. Oppengeim
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  3. V. I. Zav'yalov
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  4. K. S. Pushchevaya
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  5. V. M. Vdovin
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1547–1553, September, 1965

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Nametkin, N.S., Oppengeim, V.D., Zav'yalov, V.I. et al. Infrared absorption spectra of 1,1-substituted silicacyclobutanes, silicacyclopentanes, and the corresponding polymers. Russ Chem Bull 14, 1514–1519 (1965). https://doi.org/10.1007/BF01083790

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  • DOI: https://doi.org/10.1007/BF01083790

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