Abstract
The host-guest interactions of 2,2′-bipyridyl, 1,10-phenanthroline and 2,9-dimethyl-1,10-phenanthroline intercalated between the layers of crystallineα-zirconium monohydrogen phosphate have been studied by X-ray photoelectron spectroscopy. Evidence that, on average, only one of the two nitrogen atoms of each aromatic diamine is protonated by the ≡P-OH groups of the host is given. The acid-base interaction is strongly reduced on dehydration of the materials. The role of the cointercalated water is discussed, together with the probable disposition of the guests within the interlayer region.
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References
A. Clearfield: ‘Zirconium phosphate’ (Inorganic Ion-Exchange Materials, Ed. A. Clearfield) pp. 1–74, CRC Press, Inc., Boca Raton, Fla. (1982).
G. Alberti: Other Group (IV) Acid Salts (Inorganic Ion-Exchange Materials, Ed. A. Clearfield) pp. 75–110, CRC Press, Inc., Boca Raton, Fla. (1982).
A. Clearfield and G. D. Smith:Inorg. Chem. 8, 431 (1969).
U. Costantino, M. A. Massucci, A. La Ginestra, A. M. Tarola and L. Zampa:J. Incl. Phenom. 4, 147 (1985).
C. Ferragina, A. La Ginestra, M. A. Massucci, P. Patrono and A. A. G. Tomlinson:J. Phys. Chem. 89, 4762 (1985).
A. A. G. Tomlinson, C. Ferragina, M. A. Massucci, A. La Ginestra and P. Patrono:J. Chem. Soc., Dalton Trans. 265 (1986).
C. Ferragina, M. A. Massucci, P. Patrono, A. A. G. Tomlinson and A. La Ginestra:Mal. Res. Bull. 22, 29 (1987).
A. La Ginestra, G. Maggi, P. Galli, M. A. Massucci, C. Ferragina, P. Patrono, and A. Freeza:Chim. Ind. (Milano) 69, 109 (1987).
C. Ferragina, M. A. Massucci, P. Patrono, A. La Ginestra, and A. A. G. Tomlinson:J. Chem. Soc., Dalton Trans. 851 (1988).
A. A. G. Tomlinson, C. Ferragina, M. A. Massucci, P. Patrono, and A. La Ginestra:Proceedings of the 44th International Symposium on Inclusion Phenomena, Lancaster (U.K.), 20–25 July (1986), p. 98.
K. Siegbahn, C. Nordling, A. Fahlman, R. Nordberg, K. Hamrin, J. Hedman, G. Johansson, T. Bergmark, S. E. Karlsson, I. Lindgren and B. Lindberg:ESCA: Atomic, Molecular and Solid State Structure Studied by Means of Electron Spectroscopy, Almquist and Wiksell, Uppsala (1967).
G. Mattogno, C. Ferragina, M. A. Massucci, P. Patrono, A. La Ginestra:J. Electron Spectrosc. Relat. Phenom. 46, 285 (1988).
G. Alberti and U. Costantino: ‘Intercalation Chemistry of Acid Salts of Tetravalent Metals with Layered Structure and Related Materials’ (Intercalation Chemistry, Eds. M. S. Whittingam and A. J. Jacobson) pp. 147–179, Academic Press, New York London (1982).
T. Kijima:Thermochim Acta 59, 95 (1982).
G. Alberti and U. Costantino:J. Chromatogr. 102, 5 (1974).
C. Ferragina and M. A. Massucci: Personal communication.
A. La Ginestra, M. A. Massucci, C. Ferragina, and N. Tomassini:Therm. Anal. 1, 631 (1974).
A. Clearfield and S. P. Pack:J. Inorg. Nucl. Chem. 37, 1283 (1975).
M. Casciola, U. Costantino, L. Di Croce, and F. Marmottini:J. Incl. Phenom. 6, 291 (1988).
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Ferragina, C., Massucci, M.A. & Mattogno, G. XPS studies on the host-guest interaction of 2,2′-Bipyridyl, 1,10-phenanthroline and 2,9-dimethyl-1,10-phenanthroline intercalated inα-zirconium phosphate. J Incl Phenom Macrocycl Chem 7, 529–536 (1989). https://doi.org/10.1007/BF01080463
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DOI: https://doi.org/10.1007/BF01080463