Abstract
A simple novel and stable modification procedure for the incorporation of ferro/ferricyanide on to carbon surfaces is reported. By analysis of the voltammetric behaviour of the modified electrode in pure supporting electrolyte it is established that the incorporated species correspond to Prussian blue.
Similar content being viewed by others
References
H. Gomathi and G. Prabhakara Rao,J. Electroanal. Chem. 190 (1985) 85.
M. Fukul, C. Degrand and L. L. Miller,J. Am. Chem. Soc.,104 (1982) 28.
C. Degrand and L. L. Miller,J. Electroanal. Chem. 117 (1981) 267.
R. M. Wightman, M. R. Deakin, P. M. Kovack, W. G. Khur and K. J. Stutts,J. Electrochem. Soc. 131 (1984) 1578.
J. F. Rusling,Anal. Chem. 54 (1982) 2108.
G. N. Kamau, W. S. Willis and J. F. Rusling,Anal. Chem. 57 (1985) 545.
D. C. Thornton, K. T. Corby, V. A. Spendel, J. Jordon, A. Robbat, Jr. D. T. Rustrom, M. Gross and G. Ritzler,Anal. Chem. 57 (1985) 150.
Ing-Feg Hu, D. H. Karweik and T. Kuwana,J. Electroanal. Chem. 188 (1985) 59.
R. W. Murray in ‘Electroanalytical Chemistry’, Vol. 13 (edited by A. J. Bard) Marcel Dekker Inc., New York (1984) p. 191.
H. Gomathi, Ph.D. thesis being submitted.
K. Itaya, T. Ataka and S. Toshima,J. Am. Chem. Soc. 104 (1982) 4767.
‘Encyclopedia of Electrochemistry of Elements’, Vol VII, (edited by A. J. Bard) Marcel Dekker, New York Inc., (1976).
V. D. Neff,J. Electrochem. Soc. 125 (1978) 886.
D. Ellis, M. Echoff and V. D. Neff,J. Phys. Chem. 19 (1980) 956.
E. W. Grabner and S. Kalwellis-Mohn,J. Appl. Electrochem. 17 (1987) 653.
Masao Kaneko and Tokudo Okada,J. Electroanal. Chem. 255 (1988) 45.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Gomathi, H., Prabhakara Rao, G. Simple electrochemical immobilization of the ferro/ferricyanide redox couple on carbon electrodes. J Appl Electrochem 20, 454–456 (1990). https://doi.org/10.1007/BF01076055
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF01076055