Skip to main content
Log in

A stochastic model of deposition processes with nucleation

  • Articles
  • Published:
Journal of Statistical Physics Aims and scope Submit manuscript

Abstract

We study an interacting particle system on a one-dimensional infinite lattice and one-dimensional lattices with a periodic boundary. In this system, each site of the lattice may be either empty or occupied and initially all the lattice sites are empty. The evolution of the system is defined as follows: an empty site waits an exponential time with mean 1 and becomes occupied, and an occupied site becomes empty at a time which is distributed exponentially with meanμ k, wherek is the number of occupied neighboring sites of this site in the current state of the system. We show that the mean number of the occupied sites of the lattice, considered as a function of time, may possess a convex part. A sufficient condition for this is thatμ 0 is large andμ k,k⩾1, are small. The studied system has been proposed recently as a mathematical model of certain deposition processes, in particular those which exhibit nucleation caused by lateral attractive interaction between the deposited molecules. Our research was motivated by the observation that the density of deposited molecules contains a convex part, over some time interval, if the attractive forces are strong, while this density is a concave function of time if these forces are weak or absent. Our result agrees with this observation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. A. W. Adamson,Physical Chemistry of Surfaces, 4th ed. (Wiley-Interscience, New York, 1982).

    Google Scholar 

  2. V. Belitsky, Dynamics of spin systems on finite and infinite lattices, Ph.D. thesis, Technion-Israel Institute of Technology, Haifa, Israel (1991).

    Google Scholar 

  3. V. Belitsky and B. L. Granovsky, On the dynamics of the stochastic model of adsorption-desorption on a finite lattice,Stochastic Models 7(3):327–341 (1991).

    Google Scholar 

  4. V. Belitsky and B. L. Granovsky, Nearest neighbor spin systems: Time dynamics of the mean coverage density function and inference on parameters, preprint.

  5. A. R. Despic and M. N. Djorovic, A note on the theory of heterogeneous nucleation and growth of condensed phases,Electrochim. Acta 29(1):313–341 (1984).

    Google Scholar 

  6. B. L. Granovsky, T. Rolski, W. A. Woyczynski, and J. A. Mann, A general stochastic model of adsorption-desorption: Transient behavior,Chemometrics Intelligent Laboratory Systems 6:273–280 (1989).

    Google Scholar 

  7. R. S. Hansen and T. C. Wallace, The kinetics of adsorption of organic acids at the water-air interface,J. Phys. Chem. 63:1085–1091 (1959).

    Google Scholar 

  8. J. N. Jovicevic, V. D. Jovic, and A. R. Despic, The influence of adsorbing substances on the lead UPD onto (111) oriented silver single crystal surface,Electrochim. Acta 29(12):1625–1638 (1984).

    Google Scholar 

  9. D. M. Kolb, Physical and electrochemical properties of metal monolayers on metallic substrates,Advan. Electrochem. Electrochem. Eng. 11:125–271 (1978).

    Google Scholar 

  10. T. Liggett,Interacting Particle Systems (Springer, 1985).

  11. A. Smith and S. Fletcher, Exact solution to the mean and variance ofi-t transients corresponding to single-nucleus nucleation and growth,Electrochem. Acta 25:583–584 (1980).

    Google Scholar 

  12. A. Smith and S. Fletcher, Nucleation of two dimensional films—II. Calculation of coverage probabilities,Eledrochem. Acta 25:889–897 (1980).

    Google Scholar 

  13. B. Ycart, W. A. Woyczynski, J. Szulga, S. Reazor, and J. A. Mann, An interacting particle model of adsorption,Appl. Math. 20(3) (1989).

  14. B. Ycart, W. A. Woyczynski, J. Szulga, S. Reazor, and J. A. Mann, Monte-Carlo simulation of some interacting particle systems in the plane: Towards the theory of underpotential deposition,Chemometrics Intelligent Laboratory Systems 3:141–149 (1988).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Belitsky, V. A stochastic model of deposition processes with nucleation. J Stat Phys 70, 1233–1254 (1993). https://doi.org/10.1007/BF01049430

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01049430

Key words

Navigation