Skip to main content
SpringerLink
Log in

Long-lived polymer radicals

7. Synthesis of block copolymers by the reaction of living poly(N-acryloyl-L-valine) radical with vinyl monomers

  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Summary

When N-acryloyl-L-valine(ALV) was photo-polymerized in ethyl acetate, the resulting polymerization mixture was found to contain the living propagating radical of ALV. Synthesis of block copolymers was attempted by using the reaction of living poly(ALV) radical with some vinyl monomers. The resulting block copolymers were characterized by IR spectroscopy, dynamic thermogravimetry and pyrolysis gas chromatography.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. H. Tanaka, T. Sato, T. Otsu, Makromol. Chem.,180, 267 (1979).

    Google Scholar 

  2. T. Sato, J. Miyamoto, T. Otsu, J. Polym. Sci., Polym. Chem. Ed.,22, 3921 (1984).

    Google Scholar 

  3. H. Tanaka, T. Sato, T., Otsu, Makromol. Chem.,181, 2421 (1980).

    Google Scholar 

  4. T. Sato, T., Iwaki, T. Otsu, J. Polym. Sci., Polym. Chem. Ed.,21, 943 (1983).

    Google Scholar 

  5. T. Sato, T. Iwaki, S., Mori, T. Otsu, J. Polym. Sci., Polym. Chem, Ed.,21, 819 (1983).

    Google Scholar 

  6. T. Sato, Y. Yutani, T. Otsu, Polymer,24, 1018 (1983).

    Google Scholar 

  7. R. K., Kulkarni, H. Morawetz, J. Polym. Sci.,54, 491 (1961).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Applied Chemistry, Faculty of Engineering, Osaka City University, Sugimoto, Sumiyoshi-ku, 558, Osaka, Japan

    Tsuneyuki Sato, Yuji Yutani & Takayuki Otsu

Authors
  1. Tsuneyuki Sato
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yuji Yutani
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Takayuki Otsu
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sato, T., Yutani, Y. & Otsu, T. Long-lived polymer radicals. Polymer Bulletin 13, 453–458 (1985). https://doi.org/10.1007/BF01033344

Download citation

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01033344

Keywords

Search

Navigation