Skip to main content
SpringerLink
Log in

Coordination compounds of 2-mercapto-1-methylimidazole with platinum(II), palladium(II), rhodium(III) and ruthenium(III)

  • Full Papers
  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Summary

Complexes of 2-mercapto-1-methylimidazole (TMZ) with PtII, PdII, RhIII and RuIII of the general formulae Pt(TMZ)2Cl2, Pd(TMZ)4Cl2. Rh(TMZ)Cl3 and Ru(TMZ)Cl3 have been obtained. The thermal stabilities of the compounds were estimated by derivatographic measurements and the electron-donating atom of the measurements and the electron-donating atom of the ligand was identified from the i.r. absorbtion spectra. Lattice constants for the PtII and PdII complexes were estimated from their x-ray powder diffraction patterns.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. B. Rosenberg,Platinum Metals Rev.,15, 42 (1971).

    Google Scholar 

  2. B. Rosenberg, E. Renshaw, L. van Camp, J. Hartwick, J. Drobnik,J. Bacteriol.,93, 716 (1967).

    Google Scholar 

  3. B. Rosenberg, L. van Camp, E. Grimley, A. J. Thomson,J. Biol. Chem.,242, 1347 (1967).

    Google Scholar 

  4. B. Rosenberg, L. van Camp, J. E. Trosko, V. N. Mansour,Nature,222, 385 (1969).

    Google Scholar 

  5. B. Rosenberg, L. van Camp,Cancer Res.,30, 1799 (1970).

    Google Scholar 

  6. H. A. O. Hill, J. M. Pratt, R. J. P. Williams,Chem. Brit.,5, 156 (1969).

    Google Scholar 

  7. R. K. Szamsutbinova,Med. Zh. Uzbekistana,11, 65 (1960).

    Google Scholar 

  8. J. R. J. Sorenson,Progr. Medicinal Chem.,15, 211 (1978).

    Google Scholar 

  9. J. R. J. Sorenson,J. Med. Chem.,19, 135 (1976).

    Google Scholar 

  10. J. R. J. Sorenson,Inflammation,1, 317 (1976).

    Google Scholar 

  11. D. A. Williams, D. T. Walz, W. O. Foye,J. Pharm. Sci.,65, 126 (1976).

    Google Scholar 

  12. C. G. van Kralingen, J. Reedijk,Inorg. Chim. Acta,30 171 (1978).

    Google Scholar 

  13. C. G. van Kralingen, K. Ridder, J. Reedijk, —ibid.36, 69 (1979).

    Google Scholar 

  14. A. T. M. Marcelis, C. G. van Kralingen, J. Opschoor, J. Reedijk,Recl. Trav. Chim. Pays-Bas,99, 198 (1980).

    Google Scholar 

  15. C. G. van Kralingen, J. K. Ridder, J. Reedijk,Transition Met. Chem.,5, 73 (1980).

    Google Scholar 

  16. A. Danysz, W. Grzeda, M. Hoffman,Vademecum, PZWL, Warszawa 1981, p. 561.

    Google Scholar 

  17. S. E. Livingstone,The Chemistry of Ruthenium, Rhodium, Palladium, Osmium, Iridium and Platinum, Pergamon Press, Oxford, New York, Toronto, Sydney and Paris, 1973, p. 274.

    Google Scholar 

  18. J. W. Visser,J. Appl. Crystallogr.,2, 89 (1969).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemistry, Pedagogical School, ul. Checińska 5, 25-020, Kielce, Poland

    Marek Z. Wisniewski, Wiesław J. Surga & Beniamin Lenarcik

Authors
  1. Marek Z. Wisniewski
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Wiesław J. Surga
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Beniamin Lenarcik
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wisniewski, M.Z., Surga, W.J. & Lenarcik, B. Coordination compounds of 2-mercapto-1-methylimidazole with platinum(II), palladium(II), rhodium(III) and ruthenium(III). Transition Met Chem 15, 63–65 (1990). https://doi.org/10.1007/BF01032234

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01032234

Keywords

Search

Navigation