Skip to main content
SpringerLink
Log in

Heterobinuclear and heterotrinuclear transition-metal μ-allenyl complexes

  • Proceedings Of The US-Italy International Conference On Organic Chemistry At Clusters And Surfaces, Piemonte, Italy (July 26–31, 1992)—Part III Of III
  • Published:
Journal of Cluster Science Aims and scope Submit manuscript

Abstract

Binuclear and trinuclear transition-metal μ-allenyl complexes—especially mixedmetal complexes—are reviewed. In recent years, a number of such compounds have been prepared by use of several synthetic methods. The most general of these methods, viz. reactions of metal propargyls and of the lower nuclearity metal allenyls with low-valent metal complexes such as metal carbonyls and platinum(0) compounds, are considered in some detail. The structures of the binuclear metal μ-η1,η2- and μ-η3,η2-allenyl complexes and of the trinuclear metal μ3-η1,η2,η2-allenyl complexes—both triangular and open—are presented and compared. Trends in the1H and13C NMR spectroscopic properties of these compounds are examined. Some aspects of reaction chemistry of the heteronuclear platinum-ruthenium μ-η1,η2-allenyl complexes are presented.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. E. Sappa, A. Tiripicchio, and P. Braunstein (1985).Coord. Chem. Rev. 65, 219.

    Google Scholar 

  2. A. J. Carty (1982).Pure Appl. Chem. 54, 113.

    Google Scholar 

  3. A. Wojcicki and C. E. Shuchart (1990).Coord. Chem. Rev. 105, 35.

    Google Scholar 

  4. D. Seyferth, G. B. Womack, C. M. Archer, and J. C. Dewan (1989).Organometallics 8, 430.

    Google Scholar 

  5. D. Nucciarone, S. A. MacLaughlin, N. J. Taylor, and A. J. Carty (1988).Organometallics 7, 106.

    Google Scholar 

  6. S. Aime, D. Osella, L. Milone, and A. Tiripicchio (1983).Polyhedron 2, 77.

    Google Scholar 

  7. P. Braunstein and J. Rose,in I. Bernal (ed.),Stereochemistry of Organometallic and Inorganic Compounds (Elsevier, Amsterdam, 1989), Vol. 3, Chap. 1.

    Google Scholar 

  8. D. Nucciarone, N. J. Taylor, and A. J. Carty (1986).Organometallics 5, 1179.

    Google Scholar 

  9. C. P. Casey, L. K. Woo, P. J. Fagan, R. E. Palermo, and B. R. Adams (1987).Organometallics 6, 447.

    Google Scholar 

  10. A. Meyer, D. J. McCabe, and M. D. Curtis (1987).Organometallics 6, 1491.

    Google Scholar 

  11. R. Yáñez, J. Ros, and R. Mathieu (1991).J. Organomet. Chem. 414, 209.

    Google Scholar 

  12. G. Gervasio, D. Osella, and M. Valle (1976).Inorg. Chem. 5, 1221.

    Google Scholar 

  13. A. J. Deeming, S. Hasso, and M. Underhill (1975).J. Chem. Soc., Dalton Trans. 1614.

  14. C. E. Shuchart, R. R. Willis, A. Wojcicki, A. L. Rheingold, and B. S. Haggerty (unpublished results).

  15. C. E. Shuchart, R. R. Willis, and A. Wojcicki (unpublished results).

  16. G. H. Young, M. V. Raphael, A. Wojcicki, M. Calligaris, G. Nardin, and N. Bresciani-Pahor (1991).Organometallics 10, 1934.

    Google Scholar 

  17. C. E. Shuchart, G. H. Young, A. Wojcicki, M. Calligaris, and G. Nardin (1990).Organometallics 9, 2417.

    Google Scholar 

  18. G. H. Young, R. R. Willis, A. Wojcicki, M. Calligaris, and P. Faleschini (1992).Organometallics 11, 154.

    Google Scholar 

  19. F. Théron, M. Verny, and R. Vessière,in S. Patai (ed.),The Chemistry of the Carbon-Carbon Triple Bond (Wiley, New York, 1978), Part 1, Chap. 10.

    Google Scholar 

  20. J. Benaim, J.-Y. Merour, and J.-L. Roustan (1971).C. R. Acad. Sci. 272, 789.

    Google Scholar 

  21. D. W. Lichtenberg and A. Wojcicki (1975).J. Organomet. Chem. 94, 311.

    Google Scholar 

  22. M. Rosenblum (1974).Acc. Chem. Res. 7, 122.

    Google Scholar 

  23. A. Wojcicki,in M. Tsutsui, Y. Ishii, and Y. Huang (eds.),Fundamental Research in Organometallic Chemistry (Van Nostrand-Reinhold, New York, 1982), p. 569.

    Google Scholar 

  24. M. E. Welker (1992).Chem. Rev. 92, 97.

    Google Scholar 

  25. R. Ben-Shoshan and R. Pettit (1967).J. Am. Chem. Soc. 89, 2231.

    Google Scholar 

  26. B. Foxman, D. Marten, A. Rosan, S. Raghu, and M. Rosenblum (1977).J. Am. Chem. Soc. 99, 2160.

    Google Scholar 

  27. R. R. Willis (1992). Ph.D. dissertation, The Ohio State University.

  28. S. Attali, F. Dahan, and R. Mathieu (1986).Organometallics 5, 1376.

    Google Scholar 

  29. F. P. Pruchnik,Organometallic Chemistry of the Transition Elements (Plenum Press, New York, 1990), Chap. 6.

    Google Scholar 

  30. D. Osella and P. Raithby (private communication).

  31. V. V. Krivykh, E. S. Taits, P. V. Petrovskii, Yu. T. Struchkov, and A. I. Yanovskii (1991).Mendeleev Commun. 103.

  32. P. W. Blosser, J. C. Gallucci, and A. Wojcicki (submitted for publication).

  33. R. S. Dickson and P. J. Fraser (1974).Adv. Organomet. Chem. 12, 323.

    Google Scholar 

  34. M.-H. Cheng, G.-H. Lee, S.-M. Peng, and R.-S. Liu (1991).Organometallics 10, 3600.

    Google Scholar 

  35. C. E. Shuchart, A. Wojcicki, M. Calligaris, and P. Faleschini (unpublished results).

  36. J. Suades, F. Dahan, and R. Mathieu (1988).Organometallics 7, 47.

    Google Scholar 

  37. G. Granozzi, E. Tondello, R. Bertoncello, S. Aime, and D. Osella (1985).Inorg. Chem. 24, 570.

    Google Scholar 

  38. L. M. Jackman and S. Sternhell,Applications of Nuclear Magnetic Resonance Spectroscopy in Organic Chemistry (Pergamon Press, New York, 1969), 2nd ed., Chap. 3–3.

    Google Scholar 

  39. P. W. Blosser and A. Wojcicki (unpublished results).

  40. C. E. Shuchart, R. R. Willis, and A. Wojcicki (1992).J. Organomet. Chem. 424, 185.

    Google Scholar 

  41. R.-S. Keng and Y.-C. Lin (1990).Organometallics 9, 289.

    Google Scholar 

  42. J. Pu, T. S. Peng, A. M. Arif, and J. A. Gladysz (1992).Organometallics 11, 3232.

    Google Scholar 

  43. P. W. Blosser, D. G. Schimpff, A. Wojcicki, and M. Calligaris (unpublished results).

  44. Ch. Elschenbroich and A. Salzer,Organometallics (VCH, New York, 1992), 2nd ed., p. 295.

    Google Scholar 

  45. S. M. Breckenridge, N. J. Taylor, and A. J. Carty (1991).Organometallics 10, 837.

    Google Scholar 

  46. A. J. Carty (private communication).

  47. R. R. Willis, J. C. Gallucci, and A. Wojcicki (unpublished results).

  48. S. Raghu and M. Rosenblum (1973).J. Am. Chem. Soc. 95, 3060.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, The Ohio State University, 43210, Columbus, Ohio

    Andrew Wojcicki

Authors
  1. Andrew Wojcicki
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wojcicki, A. Heterobinuclear and heterotrinuclear transition-metal μ-allenyl complexes. J Clust Sci 4, 59–75 (1993). https://doi.org/10.1007/BF01028385

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01028385

Key words

Search

Navigation