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Studies on 4-(2-thiazolyl)-1-(2,6-diacetylpyridine)thiosemicarbazone complexes of some bivalent metal ions

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Summary

Complexes of 4-(2-thiazolyl)-1-(2,6-diacetylpyridine)-thiosemicarbazone, H2C3NSCNH(S)NHNCMeC5H3N-C(O)Me (Htdaptsc) of the compositions [M(Htdaptsc)2Cl2] [M=MnII, CoII, NiII or ZnII] [M(Htdaptsc)Cl2] [M=ZnII, CdII or HgII] and [M(tdaptsc)2] [M=MnII, CoII, NiII, CuII, or ZnII] have been prepared and characterized by elemental analyses, molar conductance, magnetic susceptibility, electronic, e.s.r. and i.r. studies, and their stereochemistries are discussed.

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References

  1. K. C. Satpathy, H. P. Mishra and G. C. Pradhan,J. Ind. Chem. Soc.,58, 844 (1981).

    Google Scholar 

  2. S. P. Agrawal and R. A. Rai,Transition Met. Chem.,1, 238 (1976).

    Google Scholar 

  3. M. C. Ganorkar and G. V. Reddy,Proc. Ann. Convention Chemists, Kurukshetra University, 16 (1979).

  4. A. I. Vogel,A Text Book of Quantitative Inorganic Analysis, ELBS and Longmans, London 1973.

    Google Scholar 

  5. B. N. Figgis and J. Lewis in, J. Lewis and R. G. Wilkins (Eds.)Modern Coordination Chemistry, Interscience, New York 1960, p. 403.

    Google Scholar 

  6. W. J. Geary,Coord. Chem. Rev. 7, 81 (1971).

    Google Scholar 

  7. A. B. P. Lever,Inorganic Electronic Spectroscopy, Elsevier, Amsterdam 1968.

    Google Scholar 

  8. A. B. P. Lever,J. Chem. Educ. 45 711 (1968).

    Google Scholar 

  9. B. N. Figgis and J. Lewis,Prog. Inorg. Chem. 6, 192 (1964).

    Google Scholar 

  10. F. A. Cotton and G. WilkinsonAdvanced Inorganic Chemistry, Wiley Eastern, New Delhi 1976, p. 916.

    Google Scholar 

  11. C. K. Jørgenson,Acta Chem. Scand.,9, 1362 (1955).

    Google Scholar 

  12. B. A. Goodman and J. B. Raynor,Adv. Inorg. Chem. Radiochem.,13, 135 (1970).

    Google Scholar 

  13. M. P. V. Mijovic and J. Walker,Chem. Soc., 3381 (1961).

  14. N. Ohkaku and K. Nakamoto,Inorg. Chem. 10, 798 (1971).

    Google Scholar 

  15. K. Nakamoto,Infrared and Raman Spectra of Inorganic and Coordination Compounds, 3rd Edit., Wiley Interscience, New York 1978, p. 239.

    Google Scholar 

  16. R. J. H. Clark,J. Chem. Soc., 1377 (1963).

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Authors and Affiliations

  1. Department of Chemistry, Banaras Hindu University, 221005, Varanasi, India

    Bachcha Singh & Urmila Srivastava

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  1. Bachcha Singh
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  2. Urmila Srivastava
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Singh, B., Srivastava, U. Studies on 4-(2-thiazolyl)-1-(2,6-diacetylpyridine)thiosemicarbazone complexes of some bivalent metal ions. Transition Met Chem 13, 241–243 (1988). https://doi.org/10.1007/BF01025663

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  • DOI: https://doi.org/10.1007/BF01025663

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