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1:1 Molybdenum(VI) citric acid complexes

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Summary

The complexes obtained by crystallisation from an aqueous solution of molybdate and citric acid (H4cit) at pH 4–8 have Mo:cit ratio 1∶1. The new complexes have been characterised by a variety of methods in the solid state and in solution. On this basis two dimeric species, [(MoO2)2O(citH)2]4− and [(MoO2)2O(cit)2]6−, and a monomeric species [MoO3(cit)OH2]4− are proposed.

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Authors and Affiliations

  1. Faculty of Chemistry, Jagiellonian University, Karasia 3, 30-060, Kraków, Poland

    Alina Samotus, Aleksandra Kanas, Magdalena Dudek, Ryszard Gryboś & Ewa Hodorowicz

Authors
  1. Alina Samotus
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  2. Aleksandra Kanas
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  3. Magdalena Dudek
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  4. Ryszard Gryboś
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  5. Ewa Hodorowicz
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Samotus, A., Kanas, A., Dudek, M. et al. 1:1 Molybdenum(VI) citric acid complexes. Transition Met Chem 16, 495–499 (1991). https://doi.org/10.1007/BF01024315

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  • DOI: https://doi.org/10.1007/BF01024315

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