Summary
Mixed ligand complexes of the type [VOLA]ClO4 where L=5-bromosalicylaldehyde (L′) or 5-nitrosalicylaldehyde (L″) and A=2, 2′-dipyridyl (A′) or 1, 10-phenanthroline (A″) have been prepared. Treatment of the mononuclear complexes, [VOLA]ClO4, withp-phenylenediamine (ppd) orm-phenylenediamine (mpd) yielded homobinuclear [VOLA-NC6H4N-LAVO](ClO4)2, complexes, which were characterised by elemental analyses, spectra, magnetic susceptibility and molar conductance measurements.
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References
R. L. Dutta and S. Ghosh,J. Inorg. Nucl. Chem.,28, 247 (1966).
R. L. Dutta, R. K. Maiti and A. K. Sinha Roy,Indian J. Chem.,22A, 577 (1983).
R. K. Kohli and P. K. Bhattacharya,J. Indian Chem. Soc.,54, 340 (1977).
A. T. Cherapakila and J. B. Stater,Ves Zaochem. Politekn. Inst.,32, 105 (1964).
C. M. Harris and E. Sinn,J. Inorg. Nucl. Chem.,30, 2723 (1968).
K. V. Patel and P. K. Bhattacharya,J. Chem. Soc., Dalton Trans., 359 (1982).
B. C. Whitmore and R. Eisenber,Inorg. Chem.,22, 1 (1983).
E. F. Hasty, T. J. Calburn and D. N. Hendrickson,Inorg. Chem.,12, 2414 (1973).
W. J. Geary,J. Co-ord. Chem. Riv.,7, 81 (1971).
K. Gopalkrishnan, U. Chudasama and P. K. Bhattacharya,J. Indian Chem. Soc.,56, 445 (1979).
K. V. Patel and P. K. Bhattacharya,Indian J. Chem.,21A, 1110 (1982).
K. V. Patel and P. K. Bhattacharya,Indian J. Chem.,23A, 527 (1984).
B. J. Pandya and P. K. Bhattacharya (communicated).
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Pandya, B.J., Bhattacharya, P.K. Mixed-ligand and binuclear complexes of oxovanadium(IV). Transition Met Chem 12, 347–349 (1987). https://doi.org/10.1007/BF01024031
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DOI: https://doi.org/10.1007/BF01024031