Summary
New compounds of chromium(I), from the interaction of potassium pentacyanonitrosylchromate(I) monohydrate, K3[CrNO(CN)5]·H2O with 2-, 3- and 4-aminopyridines, pyridine-2-hydrazide, 2(2-aminoethyl)pyridine and 4(2-aminoethyl)pyridine are described. The products possess the empirical formula, CrNO(CN)2(L)2, for which a cyano-bridged polymeric structure is proposed. Chromium(I) has a low-spin-d5 configuration in these complexes.
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Maurya, R.C., Shukla, R., Shukla, R.K. et al. Novel cyano-bridged nitrosyl complexes of chromium(I) with amino- and aminoethyl-pyridines. Transition Met Chem 12, 203–205 (1987). https://doi.org/10.1007/BF01023529
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DOI: https://doi.org/10.1007/BF01023529