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Synthesis of silicon-containing esters of phosphorus acids and study of their thermal stability. 3. Thermal rearrangement of triorganosilylmethyl esters of diphenyl phosphoric acid

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A method has been developed for the preparation of a series of triorganosilylmethyl esters of diphenylphosphoric acid.

  2. 2.

    All the triorganosilylmethyl esters of diphenylphosphoric acid which were examined undergo thermal rearrangement involving the migration of a radical from the Si atom to the methylene C atom according to a 1,2-shift. The influence of the type of radical at the Si atom on the rate of the rearrangement has been studied.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organometallic Compounds, Academy of Sciences of the USSR, Moscow

    M. I. Kabachnik, L. S. Zakharov, G. N. Molchanova, T. D. Drozdova & P. V. Petrovskii

Authors
  1. M. I. Kabachnik
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  2. L. S. Zakharov
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  3. G. N. Molchanova
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  4. T. D. Drozdova
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  5. P. V. Petrovskii
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1664–1670, July, 1989.

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Kabachnik, M.I., Zakharov, L.S., Molchanova, G.N. et al. Synthesis of silicon-containing esters of phosphorus acids and study of their thermal stability. 3. Thermal rearrangement of triorganosilylmethyl esters of diphenyl phosphoric acid. Russ Chem Bull 38, 1527–1532 (1989). https://doi.org/10.1007/BF00978452

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  • DOI: https://doi.org/10.1007/BF00978452

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