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Molecular structure of perfluoroolefin derivatives. 2. X-ray structural study of 3-p-cresoxyperfluoro-2-methylpent-2-ene

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Features of the molecular geometry of 3-p-cresoxyperfluoro-2-methylpent-2-ene are established by x-ray structural studies. Opposing steric and electronic effects of the bulky and electronegative RF-substituents on the C atoms of the double bond in the perfluoroolefins are shown practically not to change the double bond length in comparison with ethylene.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelemental Compounds, Academy of Sciences of the USSR, Moscow

    S. V. Sereda, M. Yu. Antipin, L. L. Gervits, K. N. Makarov & Yu. T. Struchkov

Authors
  1. S. V. Sereda
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  2. M. Yu. Antipin
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  3. L. L. Gervits
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  4. K. N. Makarov
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  5. Yu. T. Struchkov
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Additional information

For previous communication, see [1].

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1549–1552, July, 1989.

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Sereda, S.V., Antipin, M.Y., Gervits, L.L. et al. Molecular structure of perfluoroolefin derivatives. 2. X-ray structural study of 3-p-cresoxyperfluoro-2-methylpent-2-ene. Russ Chem Bull 38, 1416–1419 (1989). https://doi.org/10.1007/BF00978429

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  • DOI: https://doi.org/10.1007/BF00978429

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