Abstract
A review is given of thermodynamic effects arising from the following types of order in liquid components or their mixtures: quadrupolar order in benzene as shown by the benzene-cyclohexane system, orientational order in long-chain normal alkanes revealed by their mixtures with globular molecules, non-randomness in mixtures approaching phase separation, alcohol multimers in inert solvents, water-structuring around hydrophobic solutes, and micelles.
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References
I. Prigogine (with the collaboration of V. Mathot and A. Bellemans),The Molecular Theory of Solutions (North-Holland, Amsterdam, 1957).
P. J. Flory,J. Am. Chem. Soc. 87, 1833, (1965).
P. Picker, C. Jolicoeur, and J. E. Desnoyers,J. Chem. Thermodyn. 1, 469, (1969).
P. Picker, P. A. Leduc, P. R. Philip, and J. E. Desnoyers,J. Chem. Thermodyn. 3, 631 (1971).
Current Contents, January 13, 1986.
O. Kratky, H. Leopold, and H. Stabinger,Angew. Phys. 27, 273, (1969).
P. Picker, E. Tremblay, and C. Jolicoeur,J. Solution Chem. 3, 377, (1974).
M. Diaz-Peña and M. L. McGlashan,Trans. Faraday Soc. 57, 1511 (1961).
A. D. Matilla, G. Tardajos, E. Junquera, and E. Aicart,J. Solution Chem. 20, 805 (1991) and cited references.
M. L. McGlashan and K. W. Morcom,Trans. Faraday Soc. 57, 581, (1961);
M. L. McGlashan and A. G. Williamson,Trans. Faraday Soc. 57, 588 (1961);
M. L. McGlashan, K. W. Morcom, and A. G. Williamson,Trans. Faraday Soc. 57, 601 (1961).
R. N. Lichtenthaler, D. S. Abrams, and J. M. Prausnitz,Can. J. Chem. 51, 3071, (1973); R. N. Lichtenthaler, D. D. Liu, and J. M. Prausnitz,Ber. Bunsenges. Phys. Chem. 78, 470, (1974); M. D. Donohue and J. M. Prausnitz,Can. J. Chem. 53, 1586, (1975).
J. Smith, K. S. Siow, and D. Patterson,J. Chem. Soc. Faraday Trans. I 88, 1883, (1992).
T. M. Letcher and R. C. Baxter,J. Solution Chem. 18, 65, 81, 89, (1989).
H. V. Tra and D. Patterson,J. Solution Chem. 11, 793, (1982).
J. P. E. Grolier, E. Wilhelm, and M. H. Hamedi,Ber. Bunsenges Phys. Chem. 82, 1282 (1978).
J. Vrbancich and G. L. D. Ritchie,J. Chem. Soc. Faraday Trans. I 74, 3008 (1978).
A. H. Narten,J. Chem. Phys. 67, 2102 (1977).
I. E. Craven, M. R. Hesling, D. R. Laver, P. B. Lukins, G. L. D. Ritchie, and J. Vrbancich,J. Phys. Chem. 93, 627, (1989).
J. Aracil, R. G. Rubio, M. Caceres, M. Diaz Peña, and J. A. R. Renuncio,J. Chem. Soc. Faraday Trans. I 84, 539, (1988).
F. L. Swinton and J. S. Rowlinson,Liquids and Liquid Mixtures, 2nd edn., (Butterworths, London).
C. H. Twu, K. E. Gubbins, and C. G. Gray,Molecular Phys. 29, 713, (1975);
M. Flytzani-Stephanopoulos, K. E. Gubbins, and C. G. Gray,Molecular Phys. 30, 1649, (1975).
D. Patterson and M. Barbe,J. Phys. Chem. 80, 2345, (1976).
H. Soejima, H. Nakai, K. Tamura, H. Ogowa, and S. Murakami,Thermochimica Acta 177, 305, (1991).
S. Kawanishi, T. Sasuga, and M. Takehisa,J. Phys. Soc. Jpn. 51, 1579 (1982).
P. Bothorel,J. Colloid Interface Soc. 27, 529, (1968), H. Quinones and P. Bothorel,Compt. Rend. 277, 133, (1973).
M. Barbe and D. Patterson,J. Phys. Chem. 82, 40, (1978).
S. N. Bhattacharyya and D. Patterson,J. Chem. Soc. Faraday Trans. II 81, 375, (1985).
J. P. E. Grolier, A. Inglese, and E. Wilhelm,J. Chem. Thermodyn. 16, 67, (1984).
R. Rubio, M. Caceres, M. Masegosa, L. Andreoli-Ball, M. Costas, and D. Patterson,Ber. Bunsenges. Phys. Chem. 93, 48, (1989).
L. M. Trejo, M. Costas, and D. Patterson,J. Chem. Soc. Faraday Trans. 87, 3001, (1991).
M. E. St. Victor and D. Patterson,Thermochimica Acta 159, 177, (1990).
C. B. Kretschmer and R. Wiebe,J. Chem. Phys. 22, 1697, (1954).
H. Kempter and R. Mecke,Z. Phys. Chem. Abt. B 46, 229, (1940).
T. Hofman and H. Buchowski,J. Chem. Soc. Faraday Trans. 88, 689, (1992).
M. Costas and D. Patterson,J. Chem. Soc. Faraday Trans. I 81, 635, (1985).
L. Andreoli-Ball, D. Patterson, M. Costas, and M. Caceres-Alonso,J. Chem. Soc. Faraday Trans. I 84, 3991, (1988).
H. V. Kehiaian and A. J. Treszczanowicz,Bull. Acad. Chim. Fr. 5, 1561, (1969).
K. Shinoda and M. Fujihara,Bull. Chem. Soc. Japan 41, 262, (1968); K. Shinoda,J. Phys. Chem. 81, 1300 (1977).
A. Hvidt,Ann. Rev. Biophys. Bioeng.,12, 1, (1983).
R. Silveston and B. Kronberg,J. Phys. Chem. 93, 6241 (1989).
M. Costas, R. Silveston, and B. Kronberg, to be published.
P. R. Privalov,Crit. Rev. Biochem. Mol. Biol. 25, 281 (1990).
J. E. Desnoyers, G. Caron, R. de Lisi, D. Roberts, A. Roux, and G. Perron,J. Phys. Chem. 87, 1397 (1983).
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Patterson, D. Structure and the thermodynamics of non-electrolyte mixtures. J Solution Chem 23, 105–120 (1994). https://doi.org/10.1007/BF00973540
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DOI: https://doi.org/10.1007/BF00973540