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Enthalpies of formation of some phases present in the Y−Ba−Cu−O system by solution calorimetry

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Abstract

Enthalpies of some of the phases in the Y−Ba−Cu−O system were determined by solution calorimetry using a Calvet microcalorimeter. The standard enthalpies of formation for the phases were found to be YBa2Cu3O6.60, −2627.9; YBa2Cu3O6.77, −2641.8; YBa2Cu3O6.90, −2652.0; YBa2Cu3O6.99, −2659.3; Y2Cu2O5, −2198.6; Y2BaCuO5, −2656.4; BaCuO2.33, −788.6; and BaCuO2.42, −796.2 kJ-mol−1.

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References

  1. G. K. Moiseev, N. A. Vatolin, S. I. Zaizeva, N.I. Ilyinych, D. S. Tsagareishvili, G. G. Gvelesiani, I. B. Baratashvili and J. Šesták,Thermochimica Acta 198, 267 (1992).

    Google Scholar 

  2. L. R. Morss, D. C. Sonnenberger, and R. J. Thorn,Inorg. Chem. 27, 2106 (1988).

    Google Scholar 

  3. G. F. Vornonin and S. A. Degterov,Physica C 176, 387 (1991).

    Google Scholar 

  4. L. A. Reznitsky,J. Phys. Chem. (Russ) 63, 1943 (1989).

    Google Scholar 

  5. G. K. Moiseev, N. A. Vatolin, and D. S. Tsagareishvili,Rep. USSR Acad. Sci. 307, 902 (1989).

    Google Scholar 

  6. M. M. Pivovarov, M. V. Razumeenko, and M. M. Slulz,Proc. 12th All-Union Conf. on Chem. Thermodynamics and Calorimetry, Gorky 1, 4 (1988).

    Google Scholar 

  7. F. H. Garzon, I. D. Raistrick, D. S. Ginley, and J. W. Halloran,J. Mater. Res. 6, 885 (1991).

    Google Scholar 

  8. U. Wiesner, G. Krabbes, and M. Ritshel,Mater. Res. Bull. 24, 1261 (1989).

    Google Scholar 

  9. L. R. Morss, S. E. Dorss, and T. B. Lindemer,Eur. J. Solid State Inorg. Chem. 27, 327 (1989).

    Google Scholar 

  10. A. S. Monaenkova, A. A. Popova, and I. V. Zaitseva,Superconductivity: Phy., Chem. and Eng. (Russ) 3, 955 (1990).

    Google Scholar 

  11. J. Y. Skolis, S. V. Kitsenko, M. L. Kovba, and S. F. Pashin,Proc. 12th All-Union Conf. on Chem. Thermodynamics and Calorimetry, Gorky 1, 18 (1988).

    Google Scholar 

  12. Z. Hengzhong, Ph. D. Thesis, Central South University of Technology, Changsha (1991).

  13. I. Barin and O. Knacke,Thermochem. Properties of Inorg. Substances, (Springer-Verlag, Berlin, Heidelberg, New York, 1973).

    Google Scholar 

  14. I. Barin, O. Knacke and O. Kubschewski,Thermochem. Properties of Inorg. Substances (Suppl.), (Springer-Verlag, Berlin, Heidelberg, New York, 1977).

    Google Scholar 

  15. R. Pankajawalli, O. M. Sreedharan,J. Mater. Sci. Lett. 7, 714 (1988).

    Google Scholar 

  16. Z. Fan, C. Ji and Z. Zhao,J. Less-Comm. Metals 161, 49 (1990).

    Google Scholar 

  17. Z. Hengzhong, Z. Pingmin and C. Xinmin,Nonferrous Metals (Chn) 45, 61 (1993).

    Google Scholar 

  18. S. A. Schukarev, G. M. Orlova and Z. U. Borisova,Zh. Obschch. Khim. (Russ)30, 2097 (1960).

    Google Scholar 

  19. A. F. Maiorova, S. N. Mudretsova, S. F. Pashin, and M. A. Bykov,Thermochimica Acta 197, 219 (1992).

    Google Scholar 

  20. Z. Zhou and A. Navrosky,J. Mater. Res. 7, 2920 (1992).

    Google Scholar 

  21. R. Pankajavalli and O. M. Sreedharn,J. Mater. Sci. Lett. 8, 225 (1989).

    Google Scholar 

  22. P. K. Gallagher, H. M. O'Bryan, and G. S. Grader,Therochimica Acta 137, 373 (1989).

    Google Scholar 

  23. K. Conder, S. Rusiecki, and E. Kaldis,Mater. Res. Bull. 24, 581 (1989).

    Google Scholar 

  24. Z. Gan, Y. Han, and R. Zhang,Symposium on Properties of Oxide Superconductors, (Chn), (Beijing University Press, Beijing 1988).

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Central South University of Technology, 410083, Changsha, Hunan, China

    Zhang Hengzhong, Fang Zheng, Zhang Pingmin & Chen Xinmin

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  1. Zhang Hengzhong
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  2. Fang Zheng
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  3. Zhang Pingmin
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  4. Chen Xinmin
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Hengzhong, Z., Zheng, F., Pingmin, Z. et al. Enthalpies of formation of some phases present in the Y−Ba−Cu−O system by solution calorimetry. J Solution Chem 24, 565–578 (1995). https://doi.org/10.1007/BF00973207

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  • DOI: https://doi.org/10.1007/BF00973207

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