Skip to main content
SpringerLink
Log in

Excess volumes and viscosities of mixtures of nitrobenzene and certain aromatic bases

  • Published:
Journal of Solution Chemistry Aims and scope Submit manuscript

Abstract

Excess molar volumes VE, excess viscositiesη E, excess Gibbs energy changes for viscous flow ΔG‡E and interaction parameters d for binary mixtures of nitrobenzene with aniline, N-methylaniline and m-chloroaniline at selected compositions were determined from the measured values of densities and viscosities of pure components and their mixtures at 30°C. UV-visible spectra for all the binary mixtures were recorded and showed a characteristic absorption maximum. The results are analyzed in terms of interactions arising due to electrondonor-acceptor (EDA) or charge transfer (CT) complexation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. H. Ratjaczak and W. J. Orville Thomas,Molecular Interactions, Vols. I, II & III (Wiley, New York, 1989).

    Google Scholar 

  2. G. Barone, G. Castronovo, P. D. Vechio, and C. G. Giancola,J. Chem. Soc. Faraday Trans I 85, 2087 (1989).

    Google Scholar 

  3. G. Ravichandran, A. Srinivasa Rao, and T. K. Nambinarayanan,Ind. J. Pure & Appl. Phys. 31, 59 (1994).

    Google Scholar 

  4. G. Ravichandran, A. Srinivasa Rao, and T. K. Nambinarayanan,J. Pure & Appl. Ultrason. 13, 53 (1991).

    Google Scholar 

  5. V. K. Sharma, P. P. Singh, S. Maken, and Bhup Singh,Ind. J. Chem. 33A, 287 (1994).

    Google Scholar 

  6. S. Chauhan, V. K. Syal, and M. S. Chauhan,Ind. J. Pure & Appl. Phys. 32, 186 (1994).

    Google Scholar 

  7. J. Latha, S. Palaniappan, and D. N. Satyanarayana,Ind. J. Chem. 33A, 104 (1994).

    Google Scholar 

  8. V. K. Sharma, P. P. Singh, S. Maken and J. Singh,Ind. J. Chem. 33A, 727 (1994).

    Google Scholar 

  9. Organic Semi Conductors, Proc. Conf. (Macmillan, London, 1963).

  10. T. Nash and A. C. Allison,Biochem. Pharmacology (Peragmann Press, Oxford, 1963).

    Google Scholar 

  11. D. Agin,Nature,205, 805 (1965).

    Google Scholar 

  12. D. D. Perrin, W. L. F. Armareco, and D. R. Perrin,Purification Of Laboratory Chemicals (Pergamon Press, Oxford, 1980).

    Google Scholar 

  13. L. Gurnberg and A. H. Nissan,Nature 164, 799 (1949).

    Google Scholar 

  14. H. Eyringe and M. S. John,Significant Liquid Structures (Wiley, New York, 1969).

    Google Scholar 

  15. R. K. Nigam, P. P. Singh, and K. C. Singh,Can. J. Chem. 57, 2221 (1979).

    Google Scholar 

  16. V. K. Sharma, P. P. Singh, S. Maken, and Jaibir Singh,Ind. J. Chem. 33A, 727 (1994).

    Google Scholar 

  17. Christian Reichardt,Solvents and Solvent Effects in Organic Chemistry, Second edn. (VCH, Weinheim, 1990).

    Google Scholar 

  18. M. Roy and B. K. Seal,Proc. Ind. Acad. Sci. (Chem. Sci) 106, 83 (1994).

    Google Scholar 

Download references

Author information

Author notes

  1. K. Govindan

    Present address: Department of Chemistry, Pondicherry University, Pondicherry-8, India

Authors and Affiliations

  1. Raman School of Physics, Pondicherry University, Pondicherry-14, India

    G. Ravichandran

Authors
  1. K. Govindan
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. Ravichandran
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Govindan, K., Ravichandran, G. Excess volumes and viscosities of mixtures of nitrobenzene and certain aromatic bases. J Solution Chem 25, 75–82 (1996). https://doi.org/10.1007/BF00972760

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00972760

Key Words

Search

Navigation