Skip to main content
SpringerLink
Log in

Activity measurements in the ternary system NaBr+NaClO4+H2O at 25°C

  • Published:
Journal of Solution Chemistry Aims and scope Submit manuscript

Abstract

The activity coefficients of sodium bromide in the ternary system NaBr+NaClO4+H2O were determined at 25°C and constant ionic strength of 0.1, 0.5, 1, 2, and 3 mol-kg−1 from emf of the cell without, liquid junction

$$ISE - Na|NaBr(m_A ), NaClO_4 (m_B ), AgCl_{(s)} 1 Ag$$

The experimental activity coefficients were comparatively analyzed by using the Harned, Scatchard, Pitzer and Lim-HOLL treatments. All these methods are adequate for the analysis of the experimental data. The results have been compared with those of Lanier for the system: NaCl+NaClO4+H2O. The Gibbs excess energy of mixing was obtained and qualitatively interpreted in terms of ionic interactions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. P. Delahay,Double Layer and Electrode Kinetics (Wiley, New York, 1965).

    Google Scholar 

  2. J. Goodisman,Electrochemistry: Theoretical Foundations (Wiley, New York, 1987).

    Google Scholar 

  3. R. A. Durst and D. N. Hume,Anal. Chim. Acta 251, 3 (1991).

    Google Scholar 

  4. R. M. Smith and A. E. Martell,Critical Stability Constants, Vol 1–6. (Plenum Press, New York, 1974–1989).

    Google Scholar 

  5. D. D. DeFord and D. N. Hume,J. Am. Chem. Soc. 73, 5321 (1951).

    Google Scholar 

  6. H. Matsuda and Y. Ayabe,Bull. Chem. Soc. Japan 28, 422 (1955);29, 132 (1956);Z. Elektrochem.64, 1164 (1959);Rep. Gov. Chem. I. Research,. Institute,. Tokyo 61, 315 (1966);62, 107 (1967).

    Google Scholar 

  7. M. Pérez and J. L. Arbona,personal communication, 1995.

  8. A. Haghtalab and J. H. Vera,J. Chem. Eng. Data 36, 332 (1991).

    Google Scholar 

  9. J. C. Rodríguez-Placeres, M. Barrera, R. M. Fernández, and A. Arévalo,J. Electroanal. Chem. 169, 69 (1984).

    Google Scholar 

  10. K. S. Pitzer,Activity Coefficients in Electrolyte Solutions (CRC Press, Boca Raton, Florida, 1991).

    Google Scholar 

  11. S. Lakshmanan and S. K. Rangarajan,J. Electroanal. Chem. 27, 170 (1970).

    Google Scholar 

  12. F. Hernández-Luis, R. M. Dorta, and M. Barrerapersonal communication, 1995.

  13. M. A. Esteso, L. Fernández-Mérida, F. Hernández-Luis, and O. Gonzĺez-Díaz,Berl. Bunsenges Phys. Chem. 93, 213 (1989).

    Google Scholar 

  14. M. A. Esteso, F. Hernández-Luis, L. Fernández-Mérida, and O. González-Díaz,J. Solution Chem. 18, 265 (1989).

    Google Scholar 

  15. M. A. Esteso, F. Hernández-Luis, O. González-Díaz, L. Fernández-Mérida, S. K. Khoo, and T. K. Lim,J. Solution Chem. 20, 417 (1991).

    Google Scholar 

  16. A. K. Covington and J. E. Prue,J. Chem. Soc. 3696 (1955).

  17. A. J. Zielen,J. Phys. Chem. 67, 1474 (1963).

    Google Scholar 

  18. H. S. Harned and B. B. Owen,The Physical Chemistry of Electrolytic Solution, 3rd. edn. (Reinhold, New York, 1958).

    Google Scholar 

  19. H. S. Harned and R. A. Robinson,Multicomponent Electrolyte Solutions, (Pergamon Press, Oxford, 1968).

    Google Scholar 

  20. R. D. Lanier,J. Phys. Chem. 69, 3992 (1965).

    Google Scholar 

  21. T. K. Lim, S. K. Khoo, F. Hernández-Luis, L. Fernández-Mérida, and M. A. Esteso,J. Solution Chem. 22, 77 (1993).

    Google Scholar 

  22. G. ScatchardJ. Am. Chem. Soc. 91, 2410 (1969).

    Google Scholar 

  23. G. Scatchard, R. M. Rush, and J. J. Johnson,J. Phys. Chem. 74, 3786 (1970).

    Google Scholar 

  24. K. S. Pitzer,J. Phys. Chem. 77, 268 (1973).

    Google Scholar 

  25. K. S. Pitzer and J. J. Kim,J. Am. Chem. Soc. 96, 5701 (1974).

    Google Scholar 

  26. T. K. Lim, C-Y. Chan, and K. H. Khoo,J. Solution Chem. 7, 507 (1980).

    Google Scholar 

  27. T. K. Lim,Pure and Applied Chem. 65, 2561 (1993).

    Google Scholar 

  28. W.-Y. Wen, K. Miyajima, and A. Otsuka,J. Phys. Chem.,75, 2148 (1971).

    Google Scholar 

  29. D. Rosenzweig, J. Padova, and Y. Marcus,J. Phys. Chem. 80, 601 (1976).

    Google Scholar 

  30. F. Hernández-Luis, L. Fernández-Mérida, H. Galleguillos, M. A. Esteso, M. A. Esteso, K. S. Ooi, S. K. Khoo, and T. K. Lim,Fluid Phase Equilibria 109, 139 (1995).

    Google Scholar 

  31. M. A. Esteso, L. Fernández-Mérida, O. González-Díaz, and F. Hernández-Luis,Ber. Bunsenges. Phys. Chem. 93, 1114 (1989).

    Google Scholar 

  32. F. Hernández-Luis, L. Fernández-Mérida, O. González-Díaz, M. A. Esteso, S. K. Khoo, and T. K. Lim,Ber. Bunsenges. Phys. Chem.,97, 229 (1993).

    Google Scholar 

  33. M. A. Esteso, F. Hernández-Luis, L. Fernández-Mérida, and O. González-Díaz,J. Chem. Research (S), 242 (1990); (M), 1855 (1990).

  34. R. A. Robinson, R. H. Wood, and P. J. Reilly,J. Chem. Thermodyn. 3, 461 (1971).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Departmento de Química Física, Universidad de la Laguna, Tenerife, España

    F. Hernández-Luis, M. Barrera, L. Fernández-Mérida & M. Pérez

  2. Departamento de Ingeniería Química, Universidad de Antofagasta, Antofagasta, Chile

    H. R. Galleguillos

Authors
  1. F. Hernández-Luis
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. Barrera
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. H. R. Galleguillos
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. L. Fernández-Mérida
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. M. Pérez
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Hernández-Luis, F., Barrera, M., Galleguillos, H.R. et al. Activity measurements in the ternary system NaBr+NaClO4+H2O at 25°C. J Solution Chem 25, 219–229 (1996). https://doi.org/10.1007/BF00972691

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00972691

Key Words

Search

Navigation