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Catalytic hydrocondensation of carbon monoxide with olefins and their hydropolymerization by the action of carbon monoxide and hydrogen 55. Hydropolymerization of ethylene intiated by CO on cobalt catalysts containing high-silica zeolite

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Pentasil high-silica zeolite-base cobalt catalysts are active in the hydropolymerization of ethylene initiated by carbon monoxide and their activity increases with decreasing zeolite modulus.

  2. 2.

    Aromatic compounds are formed under ethylene hydropolymerization conditions on cobalt-Pentasil catalysts.

  3. 3.

    A correlation was found between the activity of these cobalt catalysts in ethylene hydropolymerization and the chemisorption of carbon monoxide.

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Literature cited

  1. N. I. Ershov, Huang Ch'ong Yem, and Ya. T. Éidus, Izv. Akad. Nauk SSSR, Ser. Khim., 894 (1974).

  2. Ya. T. Éidus, N. I. Ershov, and Huang Ch'ong Yem, Izv. Akad. Nauk SSSR, Ser. Khim., 1876 (1974).

  3. Ya. T. Éidus, A. L. Lapidus, and V. I. Mashinskii, Izv. Akad. Nauk SSSR, Ser. Khim., 1307 (1976).

  4. N. M. Popova, L. V. Babenkova, and G. A. Savenkova, The Adsorption and Interaction of Gases on Group VIII Metals [in Russian], Nauka, Alma-Ata (1979), p. 218.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    A. L. Lapidus, Huang Ch'ong Yem, A. Yu. Krylova & Ya. V. Mirskii

Authors
  1. A. L. Lapidus
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  2. Huang Ch'ong Yem
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  3. A. Yu. Krylova
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  4. Ya. V. Mirskii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2739–2743, December, 1981.

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Lapidus, A.L., Yem, H.C., Krylova, A.Y. et al. Catalytic hydrocondensation of carbon monoxide with olefins and their hydropolymerization by the action of carbon monoxide and hydrogen 55. Hydropolymerization of ethylene intiated by CO on cobalt catalysts containing high-silica zeolite. Russ Chem Bull 30, 2279–2282 (1981). https://doi.org/10.1007/BF00963687

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  • DOI: https://doi.org/10.1007/BF00963687

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