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Kinetics of the reactions of diabyliodonium salts with mercury

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study has been made of the kinetics of the reactions of diaryliodonium salts with metallic mercury in acetonitrile solution.

  2. 2.

    The reactions of the diaryliodonium chlorides with mercury are insensitive to changes in the substituent in the benzene ring of the iodonium salt.

  3. 3.

    A study has also been made of the temperature variation of the rates of decomposition of diphenyliodonium chlorides and bromides under the action of mercury in acetonitrile solution. Activation parameters have been obtained for these reactions.

  4. 4.

    Discussion is given of possible mechanisms for the reactions of these salts with mercury.

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    T. L. Kim, O. A. Ptitsyna, K. P. Butin & O. A. Reutov

Authors
  1. T. L. Kim
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  2. O. A. Ptitsyna
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  3. K. P. Butin
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  4. O. A. Reutov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2699–2703, December, 1981.

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Kim, T.L., Ptitsyna, O.A., Butin, K.P. et al. Kinetics of the reactions of diabyliodonium salts with mercury. Russ Chem Bull 30, 2244–2247 (1981). https://doi.org/10.1007/BF00963679

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  • DOI: https://doi.org/10.1007/BF00963679

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