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Absolute configuration and anisotropic polarizability of molecules. 3. Determination of polarizability ellipsoids of the C=C bond and the cyclobutane ring in molecules of the pinene series

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    An equation for gyration has been derived which accounts for the scatter of polarizability anisotropy.

  2. 2.

    A polarizability ellipsoid has been determined for the C=C double bond and the bonds that make up the cyclobutane ring.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch of the Academy of Sciences of the USSR, USSR

    S. G. Vul'fson & V. F. Nikolaev

Authors
  1. S. G. Vul'fson
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  2. V. F. Nikolaev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2259–2264, October, 1981.

The authors wish to express their profound thanks to B. A. Arbuzov and A. N. Vereshchagin for their attention to the research and their valuable comments, and to Z. G. Isaeva for making the α-pinene sample available.

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Vul'fson, S.G., Nikolaev, V.F. Absolute configuration and anisotropic polarizability of molecules. 3. Determination of polarizability ellipsoids of the C=C bond and the cyclobutane ring in molecules of the pinene series. Russ Chem Bull 30, 1854–1858 (1981). https://doi.org/10.1007/BF00963407

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  • DOI: https://doi.org/10.1007/BF00963407

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