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Kinetics of reaction between 1-lithium-2-isopropyl-o-carborane and ethyl bromide and ethyl iodide

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

By studying the kinetics of reaction between 1-lithiuni-2-isqpropyl-o-carborane and C2H5Br and C2H5I, it was found that isopropyl-o-carboranyllithium in an ether-benzene solution is tnonomeric.

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Literature cited

  1. R. N. Grimes, Carboranes, Academic Press (1970).

  2. L. I. Kruglyak, E. S. Petrov, V. N. Kalinin, E. G. Rys, L. I. Zakharkin, and A. I. Shatenshtein, Zh. Obshch. Khim.,42, 2670 (1972).

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  3. A. V. Kazantsev, Dissertation, Moscow (1966).

  4. L. I. Zakharkin and A. V. Kazantsev, Izv. Akad. Nauk SSSR, Ser. Khim., 2191 (1965).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2211–2215, October, 1981.

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Savel'eva, I.S., Kanakhina, L.N., Kazantsev, A.V. et al. Kinetics of reaction between 1-lithium-2-isopropyl-o-carborane and ethyl bromide and ethyl iodide. Russ Chem Bull 30, 1811–1815 (1981). https://doi.org/10.1007/BF00963397

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  • DOI: https://doi.org/10.1007/BF00963397

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