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Reactions of fluoroolefins with halogens in strong acid medium

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    In the reactions of tetrafluoroethylene and hexafluoropropylene in a HSO3F/SbF5 medium, a joint addition of both halogen and the fluorosulfate group to the multiple bond of the fluoroolefin takes place with the formation of the corresponding 2-haloperfluoroalkyl fluorosulfates.

  2. 2.

    Under mild conditions, hexafluoropropylene reacts with the superacid HSO3/SbF5 to form 2-hydrohexafluoropropyl fluorosulfate and 2-hydrohexafluoropropane.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    A. V. Fokin, Yu. N. Studnev, A. I. Rapkin, I. N. Krotovich, A. S. Tamarinov & O. V. Verenikin

Authors
  1. A. V. Fokin
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  2. Yu. N. Studnev
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  3. A. I. Rapkin
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  4. I. N. Krotovich
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  5. A. S. Tamarinov
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  6. O. V. Verenikin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2298–2302, October, 1985.

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Fokin, A.V., Studnev, Y.N., Rapkin, A.I. et al. Reactions of fluoroolefins with halogens in strong acid medium. Russ Chem Bull 34, 2128–2131 (1985). https://doi.org/10.1007/BF00963248

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  • DOI: https://doi.org/10.1007/BF00963248

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