Conclusions
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1.
The IR spectra have been recorded in theνMN region of complexes of Ni(II) and Pd(II) with 1,2-hydroxylaminooximes, possessing two different nitrogen-containing functional groups, and the possibility of establishing differences in the interatomic spacings of Ni-N has been demonstrated.
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2.
In complexes of the type Ni(HL)2 and Ni(HL *)2 the degree of oxidation of the nickel was the same.
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Literature cited
K. P. Naumova, A. I. Stetsenko, and L. B. Volodarskii, Zh. Obshch. Khim.,49, 2564 (1979).
S. A. D'yachenko, Yu. A. Simonov, and A. I. Stetsenko, Dokl. Akad. Nauk SSSR,244, 636 (1979).
S. V. Larionov, V. N. Kirichenko, and A. I. Stetsenko, Zh. Neorg. Khim.,23, 411 (1983).
S. V. Larionov, V. N. Kirichenko, and E. G. Boguslavskii, Abstracts of Papers of the Fourth All-Union Conference on the Chemistry of the Coordination Compounds of Mn, Co, Ni [in Russian], Tbilisi (1983), p. 86.
E. O. Schlemper and R. K. Murmann, Inorg. Chem.,22, 1077 (1983).
K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds [Russian translation], Mir, Moscow (1966), pp. 227, 252.
D. M. Adams, Metal-Ligand and Related Vibrations, Academic Press, New York (1967), p. 268.
A. Bigotto, G. Costa, V. Galasso, and G. de Alti, Spectrochim. Acta,26A, 1939 (1971).
A. Bigotto, V. Galasso, and G. de Alti, Spectrochim. Acta,27A, 1659 (1971).
Yu. Ya. Kharitonov and M. A. Sarukhanov, The Chemistry of Complexes of Metals with Hydroxylamine [in Russian], Nauka, Moscow (1977), p. 209.
J. Fujita', A. E. Martell, and K. J. Nakamoto, J. Chem. Phys.,36, 324, 36 (1962).
L. M. Sverdlov, M. A. Kovner, and E. P. Krainov, Vibrational Spectra of Polyatomic Molecules [in Russian], Nauka, Moscow (1970).
M. S. Hussain and E. O. Schlemper, Inorg. Chem.,18, 2275 (1979).
M. S. Hussain and E. O. Schlemper, Inorg. Chem.,18, 1116 (1979).
L. E. Godycki and R. E. Rundle, Acta Crystallogr.,6, 487 (1953).
I. M. Cheremisina, Zh. Strukt. Khim.,19, 336 (1978).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2228–2231, October, 1985.
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Oglezneva, I.M., Larionov, S.V. & Kirichenko, V.N. IR Spectra in the region of the stretching vibrations of the metal-ligand bond of complexes of Ni(II) with 1,2-hydroxylaminooximes. Russ Chem Bull 34, 2060–2063 (1985). https://doi.org/10.1007/BF00963233
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DOI: https://doi.org/10.1007/BF00963233