Conclusions
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1.
The first ionization potentials (I1 D) of peralkylated and chloro-substituted organopolysilanes were determined by electron spectroscopy.
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2.
In oxidation of organopolysilanes by peroxybenzoic acid, the reaction is retarded with increasing values of I1 D in the range of individually taken series of permethylated or chloro-substituted polysilanes. Replacement of an alkyl group at Si by a Cl atom leads to acceleration of the reaction, despite an increase of I1 D.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimieheskaya, No. 10, pp. 2177–2180, October, 1985.
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Razuvaev, G.A., Brevnova, T.N., Semenov, V.V. et al. Mechanism of oxidation of organopolysilanes by peroxy acids. Russ Chem Bull 34, 2010–2013 (1985). https://doi.org/10.1007/BF00963223
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DOI: https://doi.org/10.1007/BF00963223