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Isomeric transformations of perfluoro-1-vinyl- and perfluoro-1,3-divinylindanes by the action of SbF5 and CsF

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Perfluoro-1-vinylindane converts by the action of SbF5 or CsF into perfluorinated 1-ethylideneindane, 3-ethylindene or a mixture thereof. In the presence of SbF5, perfluoro-1-divinylindane converts into perfluoro-1-ethylidene-3-ethylindene.

  2. 2.

    When perfluoro-1,3-divinylindane, perfluoro-1-ethylidene-3-ethylindene or 1-hydroperfluoro-1,3-diethylindene are dissolved in a CsF-MeCN system, a perfluoro-1,3-diethylindenyl anion is generated.

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Authors and Affiliations

  1. Novosibirsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR

    I. P. Chuikov, V. M. Karpov, V. E. Platonov & G. G. Yakobson

Authors
  1. I. P. Chuikov
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  2. V. M. Karpov
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  3. V. E. Platonov
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  4. G. G. Yakobson
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Additional information

Deceased.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1654–1660, July, 1988.

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Chuikov, I.P., Karpov, V.M., Platonov, V.E. et al. Isomeric transformations of perfluoro-1-vinyl- and perfluoro-1,3-divinylindanes by the action of SbF5 and CsF. Russ Chem Bull 37, 1469–1475 (1988). https://doi.org/10.1007/BF00962765

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  • DOI: https://doi.org/10.1007/BF00962765

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