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Investigation of the charge state of heteroatoms in organic compounds of period III elements by x-ray fluorescence spectroscopy. 5. Sulfonic acids and their salts

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    We have observed an increase in the positive charge on the S atom in organylammonium salts of sulfonic acids (relative to the original sulfonic acids) due to the appearance of a negative charge at the O atom of the sulfo group.

  2. 2.

    The large values of the positive charge at the S atom in the inorganic sulfates compared with the organic ones may be explained by the presence of structures of the type O−-SO2-O−.

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Literature cited

  1. T. I. Rozova, G. V. Ratovskii, G. N. Dolenko, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 1287 (1987).

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR

    G. N. Dolenko, A. L. Litvin, A. I. Botbaev, D. A. Abdybaliev & R. A. Takyrbasheva

  2. Institute of Organic Chemistry, Academy of Sciences of the Khirgiz SSR, Frunze

    G. N. Dolenko, A. L. Litvin, A. I. Botbaev, D. A. Abdybaliev & R. A. Takyrbasheva

Authors
  1. G. N. Dolenko
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  2. A. L. Litvin
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  3. A. I. Botbaev
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  4. D. A. Abdybaliev
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  5. R. A. Takyrbasheva
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1565–1566, July, 1988.

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Dolenko, G.N., Litvin, A.L., Botbaev, A.I. et al. Investigation of the charge state of heteroatoms in organic compounds of period III elements by x-ray fluorescence spectroscopy. 5. Sulfonic acids and their salts. Russ Chem Bull 37, 1383–1384 (1988). https://doi.org/10.1007/BF00962745

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  • DOI: https://doi.org/10.1007/BF00962745

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