Conclusions
The shift of the position of the conformational equilibria in series of formic acid derivatives is determined primarily by steric factors.
Similar content being viewed by others
Literature cited
J. R. Larson, N. D. Epiotis, and F. Bernardi, J. Am. Chem. Soc.,100, 5713 (1978).
N. D. Epiotis, W. R. Cherry, S. Shaik, et al., Topics Curr. Chem.,70, 250 (1977).
E. Noe, T. Sanders, M. Garahi, et al., J. Am. Chem. Soc.,107., 4785 (1985).
W. H. Hocking, Z. Naturforsch.,31A, 1113 (1976).
T. B. Grindley, Tetrahedron Lett.,23, 1757 (1982).
A. van Es and W. Stevens, Rec. Trav. Chim.,84, 1247 (1965).
A. Jaeschke, H. Muensch, H. G. Schid, et al., J. Mol. Spectrosc,31, 14 (1969).
O. Exner, in: Correlation Analysis in Chemistry, Recent Advances, Plenum Press, New York-London (1978), p. 439.
M. Nogradi, Stereochemistry [Russian translation], Mir, Moscow (1984), p. 149.
M. E. Squillacote and J. M. Neth, J. Am. Chem. Soc.,109, 198 (1987).
U. Burkert and N. Allinger, Molecular Mechanics [Russian translation], Mir, Moscow (1986), p. 114.
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1552–1555, July, 1988.
Rights and permissions
About this article
Cite this article
Bredikhin, A.A., Chernov, P.P., Klochkov, V.V. et al. Parameters of the conformational equilibrium in phenyl formate. Russ Chem Bull 37, 1371–1373 (1988). https://doi.org/10.1007/BF00962742
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00962742