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Preparation and reactivity of metal-containing monomers. 7. Synthesis and study of transition metal acrylates

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The composition, structure, and properties of Co(II), Ni(II), Cu(II), Fe(III), and Cr(III) acrylates were characterized. The parameters of the multiple bond of the MCM did not change significantly when the nature of the transition metal was varied.

  2. 2.

    The formation of a binuclear cluster with a distance of Cu...Cu=2.609 Å with square-pyramidal coordination of the O atoms is a feature of the molecular structure of copper acrylate.

  3. 3.

    The predominantly ionic character of the metal-ligand bond with a degree of covalence of 0.13–0.16 was established.

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Authors and Affiliations

  1. Branch of the Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka

    G. I. Dzhardimalieva, A. D. Pomogailo, V. I. Ponomarev, L. O. Atovmyan, Yu. M. Shul'ga & A. G. Starikov

Authors
  1. G. I. Dzhardimalieva
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  2. A. D. Pomogailo
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  3. V. I. Ponomarev
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  4. L. O. Atovmyan
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  5. Yu. M. Shul'ga
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  6. A. G. Starikov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1525–1530, July, 1988.

We would like to thank I. N. Ivlev for conducting the magnetic measurements.

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Dzhardimalieva, G.I., Pomogailo, A.D., Ponomarev, V.I. et al. Preparation and reactivity of metal-containing monomers. 7. Synthesis and study of transition metal acrylates. Russ Chem Bull 37, 1346–1351 (1988). https://doi.org/10.1007/BF00962737

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  • DOI: https://doi.org/10.1007/BF00962737

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