Skip to main content
SpringerLink
Log in

Triplet exciplexes of nitrofuran derivatives with aromatic amines

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The energy of the triplet electronically excited state in 5-(4-R-1-quinolyl)-2-nitrofurans and 5-nitropyromucic acid is localized chiefly on the chain of π-electron conjugation of the molecules.

  2. 2.

    With an increase in the length of the chain of π-electron conjugation in nitrofuran derivatives their reduction potential in the triplet electronically excited state decreases; this, in turn, decreases the rate constant for interaction of the triplet state with electron donors — amines.

  3. 3.

    As a result of interation of the triplet states of the investigated nitrofuran derivatives with tertiary aromatic amines in dioxane one observes the formation of triplet exciplexes, the principal contribution to the structure of which is made by a state with complete charge transfer, whereas their deactivation is realized via reverse charge transfer as a result of decomposition of the nitrofuran anion radical.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. P. P. Levin and V. A. Kuz'min, Usp. Khim.,56, 528 (1987).

    Google Scholar 

  2. P. P. Levin and V. A. Kuz'min, Izv. Akad. Nauk SSSR, Ser. Khim., 298 (1988).

  3. T. J. Kemp and J. A. Martins, J. Chem. Soc., Faraday Trans.,1, 77, 1425 (1981).

    Google Scholar 

  4. V. B. Luzhkov and I. V. Khudyakov, Izv. Akad. Nauk SSSR, Ser. Khim., 653 (1979).

  5. C. R. Bock, J. A. Conner, A. R. Gutierres, et al., J. Am. Chem. Soc.,101, 4815 (1979).

    Google Scholar 

  6. R. F. Large, Photographic Sensitivity, R. J. Cox, New York-London (1973), pp. 241–263.

    Google Scholar 

  7. Yu. E. Borisevich, V. A. Kuz'min, I. V. Renge, and A. P. Darmanyan, Izv. Akad. Nauk SSSR, Ser. Khim., 2014 (1981).

  8. Yu. E. Borisevich, V. A. Kuz'min, and I. V. Renge, Izv. Akad. Nauk SSSR, Ser. Khim., 1796 (1981).

  9. I. V. Khudyakov, V. B. Luzhkov, and V. A. Kuz'min, Dokl. Akad. Nauk SSSR,246, 379 (1979).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    V. A. Kuz'min, P. P. Levin, Yu. E. Borisevich, I. A. Degterev & S. M. Smirnov

Authors
  1. V. A. Kuz'min
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. P. P. Levin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu. E. Borisevich
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. I. A. Degterev
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. S. M. Smirnov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1510–1514, July, 1988.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kuz'min, V.A., Levin, P.P., Borisevich, Y.E. et al. Triplet exciplexes of nitrofuran derivatives with aromatic amines. Russ Chem Bull 37, 1333–1337 (1988). https://doi.org/10.1007/BF00962733

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00962733

Keywords

Search

Navigation