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Complexes of alkali metals, magnesium, and calcium with phosphoryl-containing pendant tetraazamacrocyclic ligands

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction of lithium, sodium, potassium, and cesium 2,4-dinitrophenoxides and magnesium and calcium iodides with a number of phosphoryl-containing pendant tetraazamacrocyclic ligands L in nonaqueous solvents was studied.

  2. 2.

    The stability constants of complexes of alkali metals with the composition [ML]+ and of magnesium and calcium with the composition [MLI]+ with the indicated ligands were determined.

  3. 3.

    Among the investigated macrocyclic compounds, the ligand that contains a 14-membered macroring and an ethylene bridge in the side chain is the most effective complexing agent.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    K. B. Yatsimirskii, M. I. Kabachnik, É. I. Sinyavskaya, L. V. Tsymbal, S. A. Pisareva & T. Ya. Medved'

  2. Institute of Physical Chemistry, Academy of Sciences of the Ukrainian SSR, Kiev

    K. B. Yatsimirskii, M. I. Kabachnik, É. I. Sinyavskaya, L. V. Tsymbal, S. A. Pisareva & T. Ya. Medved'

Authors
  1. K. B. Yatsimirskii
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  2. M. I. Kabachnik
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  3. É. I. Sinyavskaya
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  4. L. V. Tsymbal
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  5. S. A. Pisareva
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  6. T. Ya. Medved'
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Additional information

Deceased.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2088–2094, September, 1988.

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Yatsimirskii, K.B., Kabachnik, M.I., Sinyavskaya, É.I. et al. Complexes of alkali metals, magnesium, and calcium with phosphoryl-containing pendant tetraazamacrocyclic ligands. Russ Chem Bull 37, 1874–1879 (1988). https://doi.org/10.1007/BF00962505

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  • DOI: https://doi.org/10.1007/BF00962505

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