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Interaction of 2-furanylmethyl- and 2-thienylmethyl-amide derivatives of 1,3-di(carboxymethyl)calix[4]arene with metal salts

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Abstract

The synthesis and metal-ion complexation properties of two new derivatives of 1,3-di(carboxymethyl)-p-tert-butylcalix[4]arene, bis(2-thienylmethylamide) 3 and bis(furanylmethylamide) 4, have been studied using UV/Vis spectrophotometry and, in some cases, 1H-NMR spectroscopy. The cations examined are alkali metals (Li+, Na+, K+, Rb+ and Cs+), alkaline earth metals (Mg2+, Ca2+, Sr2+ and Ba2+), heavy metals (Ag+, Cd2+, Hg2+ and Pb2+), and lanthanides (La3+, Nd3+, Eu3+, Gd3+ and Yb3+).

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Acknowledgements

This work was supported by Laboratory of Applied Chemistry and Natural Substances Resources and Environment (LACReSNE) Bizerte – Tunisia and Department of Chemistry Sciences and Arts College in the Al-Rass province Al-Qassim University – KSA. The authors gratefully acknowledge Qassim University, represented by the Deanship of Scientific Research.

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Authors and Affiliations

  1. Laboratory of Applied Chemistry and Natural Substances Resources and Environment (LACReSNE), Faculty of Sciences at Bizerte, 7021, Zarzouna-Bizerte, Tunisia

    Mohamed Habib Noamane, Amel Ben Othmen & Abdelwaheb Hamdi

  2. Department of Chemistry Sciences and Arts College, Al-Qassim University, BP35, Buraydah, Al-Rass, Kingdom of Saudi Arabia

    Abdullah Sulaiman Al-Ayed & Abdelwaheb Hamdi

  3. IROAST, Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto, 860-8555, Japan

    Yang Kim

  4. Department of Chemistry, Faculty of Advanced Science & Technology, Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto, 860-8555, Japan

    Shinya Hayami

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  1. Mohamed Habib Noamane
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  2. Amel Ben Othmen
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  3. Abdullah Sulaiman Al-Ayed
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  4. Yang Kim
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  5. Shinya Hayami
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  6. Abdelwaheb Hamdi
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Correspondence to Abdelwaheb Hamdi.

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Dedicated to Prof. Karsten Gloe on the occasion of his 70th birthday.

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Noamane, M.H., Ben Othmen, A., Al-Ayed, A.S. et al. Interaction of 2-furanylmethyl- and 2-thienylmethyl-amide derivatives of 1,3-di(carboxymethyl)calix[4]arene with metal salts. J Incl Phenom Macrocycl Chem 94, 249–256 (2019). https://doi.org/10.1007/s10847-019-00908-8

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