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Thermodynamics and kinetics of the complexing of thallium 3,6-di-tertbutyl-o-benzosemiquinolates with some complexing agents

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Complexes of thallium o-benzosemiquinolates with neutral organophosphorus ligands were detected by EPR spectroscopy. The thermodynamic and kinetic parameters of the complexing process were calculated.

  2. 2.

    The mobility of the ligand plays a decisive role in the coordination of the ligand with thallium o-semiquinolate.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    A. I. Prokof'ev, B. K. Shcherbakov, N. A. Malysheva, N. N. Bubnov, S. P. Solodovnikov, Yu. M. Polikarpov & M. I. Kabachnik

Authors
  1. A. I. Prokof'ev
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  2. B. K. Shcherbakov
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  3. N. A. Malysheva
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  4. N. N. Bubnov
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  5. S. P. Solodovnikov
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  6. Yu. M. Polikarpov
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  7. M. I. Kabachnik
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2074–2080, September, 1988.

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Prokof'ev, A.I., Shcherbakov, B.K., Malysheva, N.A. et al. Thermodynamics and kinetics of the complexing of thallium 3,6-di-tertbutyl-o-benzosemiquinolates with some complexing agents. Russ Chem Bull 37, 1859–1865 (1988). https://doi.org/10.1007/BF00962503

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  • DOI: https://doi.org/10.1007/BF00962503

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