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Study of the state of heteropolyanions of Mo(Vl) and W(VI) with aluminum (III) and gallium (III) in aqueous solutions by the NMR method using27Al,71Ga, and other nuclei

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    From the17O,27Al,71Ga, and183W NMR spectra, we have established that the structure of heteropolyanions of dissolved heteropoly compounds K3[Al(OH)6;Mo6O18], K3[Ga(OH)6Mo6O18] and H5[GaW12O40] is retained in aqueous solutions.

  2. 2.

    The27Al(71Ga) NMR spectra are sufficiently characteristic for identification of anions of hexamolybdate and dodecatungstates of aluminum (gallium) in aqueous solutions.

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Authors and Affiliations

  1. Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk

    M. A. Fedotov & L. P. Kazanskii

  2. Institute of Physical Chemistry, Academy of Sciences of the USSR, Moscow

    M. A. Fedotov & L. P. Kazanskii

Authors
  1. M. A. Fedotov
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  2. L. P. Kazanskii
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2000–2003, September, 1988.

The authors thank L. V. Tumurov for synthesizing the gallium tungstic acid.

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Fedotov, M.A., Kazanskii, L.P. Study of the state of heteropolyanions of Mo(Vl) and W(VI) with aluminum (III) and gallium (III) in aqueous solutions by the NMR method using27Al,71Ga, and other nuclei. Russ Chem Bull 37, 1789–1792 (1988). https://doi.org/10.1007/BF00962489

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  • DOI: https://doi.org/10.1007/BF00962489

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