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Hydrolysis of cyclopentadienyl zirconium complexes containing chelate ligands

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Hydrolysis of cyclopentadienyl β-diketonate zirconium derivatives leads to a series of novel heteroligand mono-, di-, and trinuclear complexes, which contain cyclopentadienyl, hydroxyl, β-diketonate, chloride, and nitrate ligands in various orders.

  2. 2.

    The complexes obtained in this manner undergo facile exchange of hydroxyl ligands by β-diketonates.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Hetroorganic Chemistry, Academy of Sciences of the USSR, Moscow

    M. Kh. Minacheva, É. M. Brainina, O. A. Mikhailova, Z. S. Klemenkova, B. V. Lokshin, O. D. Rudyakova & G. I. Timofeeva

Authors
  1. M. Kh. Minacheva
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  2. É. M. Brainina
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  3. O. A. Mikhailova
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  4. Z. S. Klemenkova
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  5. B. V. Lokshin
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  6. O. D. Rudyakova
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  7. G. I. Timofeeva
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 897–903, April, 1987.

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Minacheva, M.K., Brainina, É.M., Mikhailova, O.A. et al. Hydrolysis of cyclopentadienyl zirconium complexes containing chelate ligands. Russ Chem Bull 36, 824–829 (1987). https://doi.org/10.1007/BF00962331

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  • DOI: https://doi.org/10.1007/BF00962331

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