Conclusions
Neutral and cationic carbonyl-containing palladium (II) complexes with phosphine ligands have been synthesized; they are not very stable in solution and undergo disproportionation to give palladium (0) and (II) compounds. The structure of one of these disproportionation products, namely, tris(triphenylphosphine)palladium, was solved by x-ray structural analysis.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 894–897, April, 1987.
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Stromnova, T.A., Sergienko, V.S., Kisin, A.V. et al. Reaction of palladium (I) carbonyl acetate with phosphorus-containing ligands and the molecular structure of tris(triphenylphosphine)palladium. Russ Chem Bull 36, 821–824 (1987). https://doi.org/10.1007/BF00962330
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DOI: https://doi.org/10.1007/BF00962330