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Cleavage of α,Β- and Β,υ-mono- and diunsaturated organyl alkenyl sulfides by trialkyl- and trialkoxysilanes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Organyl alkenyl sulfides of general formula RS(CH2)nCH=CH2 react with triethyl- and triethoxysilane in the presence of PdCl2(C6H5CN)2 and P(C6H5)3, with cleavage of the S-C bond and the formation of the corresponding Si-substituted organylthiosilanes RSSiR3' and disilthianes R3'SiSSiR3'. The reaction is accompanied by the disproportionation of the starting silanes R3'SiH with the formation of R4'Si. Hydrosilylation products were not detected.

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    M. G. Voronkov, N. N. Vlasova & S. A. Bol'shakova

Authors
  1. M. G. Voronkov
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  2. N. N. Vlasova
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  3. S. A. Bol'shakova
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 170–173, January, 1981.

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Voronkov, M.G., Vlasova, N.N. & Bol'shakova, S.A. Cleavage of α,Β- and Β,υ-mono- and diunsaturated organyl alkenyl sulfides by trialkyl- and trialkoxysilanes. Russ Chem Bull 30, 148–151 (1981). https://doi.org/10.1007/BF00962272

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  • DOI: https://doi.org/10.1007/BF00962272

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