Skip to main content
SpringerLink
Log in

Mechanism of the retardation of oxidation reactions by metal complexes

5. The steric effect in chain termination at nickel bis(N-phenylanthranilate)

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The rate constants for the reactions of arylalkylperoxyl radicals with nickel bis(N-phenylanthranilate) decreases with substitution of the hydrogen atoms by CH3 groups at theα-carbon atom of the radical on account of steric factors.

  2. 2.

    The antioxidative properties of N-phenylanthranilic acid in the oxidation of ethylbenzene and isopropylbenzene are increased by its coordination with Ni(II).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. G. A. Kovtun, D. L. Lysenko, A. S. Berenblyum, and I. I. Moiseev, Izv. Akad. Nauk SSSR, Ser. Khim., 1266 (1980).

  2. G. A. Kovtun, D. L. Lysenko, A. S. Berenblyum, and I. I. Moiseev, Izv. Akad. Nauk SSSR, Ser. Khim., 786 (1980).

  3. J. S. Decker and H. Frye, Z. Naturforsch,21b, 522 (1966).

    Google Scholar 

  4. E. T. Denisov, Rate Constants of Homolytic Liquid-Phase Reactions [in Russian], Nauka (1973).

  5. N. M. émanuél', E. T. Denisov, Z. K. Maizus, Chain Reactions in the Liquid-Phase Oxidation of Hydrocarbons [in Russian], Nauka (1964).

  6. G. A. Kovtun, Thesis [in Russian], Moscow (1974).

  7. A. L. Aleksandrov, G. I. Solov'ev, and E. T. Denisov, Izv. Akad. Nauk SSSR, Ser. Khim., 1527 (1972).

  8. V. G. Vinogradova, A. N. Zverev, and Z. K. Maizus, Kinet. Katal.,15, 323 (1974).

    Google Scholar 

  9. A. L. Buchachenko and A. M. Vasserman, Stable Radicals [in Russian], Khimiya (1973).

  10. V. N. Vetchinkina, Z. K. Maizus, I. P. Skibida, and N. M. émanuél', Dokl. Akad. Nauk SSSR,177, 625 (1967).

    Google Scholar 

  11. G. A. Kovtun, Collection: Chemical Kinetics and Catalysis [in Russian], Nauka (1979), p. 5.

  12. G. A. Kovtun, Zh. Org. Khim.,14, 2475 (1978).

    Google Scholar 

  13. G. A. Kovtun and G. V. Pavlyuk, Dokl. Akad. Nauk UkR. SSR, Ser. B, 725 (1978).

    Google Scholar 

  14. G. A. Kovtun, A. S. Berenblyum, and I. I. Moiseev, Metal-Containing Antioxidants for Petroleum Products [in Russian], TsNIITENeftekhim, Moscow (1978).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow

    G. A. Kovtun, D. L. Lysenko, A. S. Berenblyum & I. I. Moiseev

  2. élektrogorsk Branch, All-Union Scientific-Research Institute of Petroleum Processing, USSR

    G. A. Kovtun, D. L. Lysenko, A. S. Berenblyum & I. I. Moiseev

Authors
  1. G. A. Kovtun
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. L. Lysenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. S. Berenblyum
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. I. I. Moiseev
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

For Communication 4, see [1].

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 101–106, January, 1981.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kovtun, G.A., Lysenko, D.L., Berenblyum, A.S. et al. Mechanism of the retardation of oxidation reactions by metal complexes. Russ Chem Bull 30, 79–83 (1981). https://doi.org/10.1007/BF00962258

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00962258

Keywords

Search

Navigation