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13C nuclear magnetic relaxation study of complexing of alcohols, carbohydrates, and dioxane in dimethyl sulfoxide

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The values of the auto- and cross-correlation times of the CH vectors of molecules of alcohols, carbohydrates, and 1,4-dioxane in DMSO were obtained with the method of13C nuclear magnetic relaxation. A comparison of the experimental values and the values of the correlation times calculated with the modified Kirkwood-Steele-Huntress theory showed that the cross-correlation times can be used for predicting the most probable conformations of the molecules in solutions.

  2. 2.

    It was found that the probability of formation of an OH ... DMSO complex increases with an increase in the number of OH groups in the molecule.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    V. A. Daragan & E. é. Il'ina

Authors
  1. V. A. Daragan
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  2. E. é. Il'ina
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1277–1281, June, 1988.

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Daragan, V.A., Il'ina, E.é. 13C nuclear magnetic relaxation study of complexing of alcohols, carbohydrates, and dioxane in dimethyl sulfoxide. Russ Chem Bull 37, 1124–1127 (1988). https://doi.org/10.1007/BF00961914

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  • DOI: https://doi.org/10.1007/BF00961914

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